A tandem annulation with a [1,3]-hydride transfer as the key step leading to isochromans
文献类型:期刊论文
| 作者 | Wang, YW; Li, GX; Liu, HX; Tang, Z; Cao, Y; Zhao, G; Zhao, G (reprint author), Sichuan Univ, Sch Chem Engn, Dept Pharmaceut & Biol Engn, Chengdu 610065, Sichuan, Peoples R China.; Tang, Z (reprint author), Chinese Acad Sci, Nat Prod Res Ctr Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China. |
| 刊名 | CHEMICAL COMMUNICATIONS
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| 出版日期 | 2017 |
| 卷号 | 53期号:77页码:10652-10655 |
| DOI | 10.1039/c7cc06144g |
| 产权排序 | 2 |
| 文献子类 | Article |
| 英文摘要 | An unprecedented method that enables the direct coupling of an alpha-C-H bond in alcohols with 2-arylacetaldehydes through a [1,3]-hydride transfer ([1,3]-HT) of oxocarbenium ions catalyzed by a Lewis acid has been developed. The redox neutral preparation of the isochroman derivatives proceeds via a tandem condensation/[1,3]-HT/Friedel-Crafts sequence with moderate to good yields. Deuterium-labeling studies provide mechanistic insights and reveal that the redox functionalization proceeds via a [1,3]-HT. |
| 学科主题 | Chemistry |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/29208] ![]() |
| 专题 | 成都生物研究所_天然产物研究 |
| 通讯作者 | Zhao, G (reprint author), Sichuan Univ, Sch Chem Engn, Dept Pharmaceut & Biol Engn, Chengdu 610065, Sichuan, Peoples R China.; Tang, Z (reprint author), Chinese Acad Sci, Nat Prod Res Ctr Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wang, YW,Li, GX,Liu, HX,et al. A tandem annulation with a [1,3]-hydride transfer as the key step leading to isochromans[J]. CHEMICAL COMMUNICATIONS,2017,53(77):10652-10655. |
| APA | Wang, YW.,Li, GX.,Liu, HX.,Tang, Z.,Cao, Y.,...&Tang, Z .(2017).A tandem annulation with a [1,3]-hydride transfer as the key step leading to isochromans.CHEMICAL COMMUNICATIONS,53(77),10652-10655. |
| MLA | Wang, YW,et al."A tandem annulation with a [1,3]-hydride transfer as the key step leading to isochromans".CHEMICAL COMMUNICATIONS 53.77(2017):10652-10655. |
入库方式: OAI收割
来源:成都生物研究所
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