Influence of magmatic intrusions on organic nitrogen in coal: A case study from the Zhuji mine, the Huainan coalfield, China
文献类型：期刊论文
| 作者 | Liu Guijian1,2; Fu Biao1; Yuan Zijiao1; Chen Bingyu1; Ding Dianshi1,2 |
| 刊名 | FUEL
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 219期号:2018页码:88-93 |
| 关键词 | Nitrogen Form Xps Magmatic Intrusion Huainan Coalfield |
| DOI | 10.1016/j.fuel.2018.01.081 |
| 文献子类 | Article |
| 英文摘要 | Although the influence of magmatic intrusions on coal has been studied extensively at many locations, data on changes of organic nitrogen forms in coal in response to this kind of geological instantaneous heating is still scarce. To fill this information gap, a total of five coal samples, including four coal samples collected along a coal transect approaching a magmatic intrusion and one unaltered coal sample, were collected from the No. 3 coal seam of the Zhuji mine in the Huainan coalfield, China and were analyzed for organic nitrogen forms using X-ray photoelectron spectroscopy (XPS), together with the determination of coal quality parameters and elemental composition. Due to the effect of magmatic intrusion, ash yield and carbon content of the coals increase, whereas moisture, volatile matter, oxygen, nitrogen and total sulfur decrease. The N-5 peak is dominant in unaltered and moderately altered coals, but disappears entirely in the coals adjacent to the magmatic intrusion due to the strong thermal influence. The N-Q peak mainly represents "protonated" quaternary nitrogen in unaltered and moderately altered coals. The N-Q peak can be transformed to the N-6 peak through the deprotonation of "protonated" quaternary nitrogen resulting from the loss of oxygen groups under the thermal influence of the magmatic intrusion. Closer to the magmatic intrusion, the N-Q peak is assigned to "graphitic" quaternary nitrogen, which increases sharply and becomes the predominant form eventually. Magmatic intrusion is responsible for the conversion of less stable nitrogen forms to more stable forms in coal. |
| WOS关键词 | NORTH CHINA ; ILLINOIS BASIN ; CONTACT-METAMORPHISM ; IGNEOUS INTRUSIONS ; HUAIBEI COALFIELDS ; BITUMINOUS COAL ; PERMIAN COALS ; INTRUDED COAL ; GEOCHEMISTRY ; PYROLYSIS |
| WOS研究方向 | Energy & Fuels ; Engineering |
| WOS记录号 | WOS:000429417300010 |
| 源URL | [http://ir.ieecas.cn/handle/361006/5206]  |
| 专题 | 地球环境研究所_黄土与第四纪地质国家重点实验室（2010~） |
| 作者单位 | 1.Univ Sci & Technol China, Sch Earth & Space Sci, CAS Key Lab Crust Mantle Mat & Environm, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710075, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Guijian,Fu Biao,Yuan Zijiao,et al. Influence of magmatic intrusions on organic nitrogen in coal: A case study from the Zhuji mine, the Huainan coalfield, China[J]. FUEL,2018,219(2018):88-93. |
| APA | Liu Guijian,Fu Biao,Yuan Zijiao,Chen Bingyu,&Ding Dianshi.(2018).Influence of magmatic intrusions on organic nitrogen in coal: A case study from the Zhuji mine, the Huainan coalfield, China.FUEL,219(2018),88-93. |
| MLA | Liu Guijian,et al."Influence of magmatic intrusions on organic nitrogen in coal: A case study from the Zhuji mine, the Huainan coalfield, China".FUEL 219.2018(2018):88-93. |
入库方式： OAI收割
来源：地球环境研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。