Two Possible Side Reaction Pathways during Furanic Etherification
文献类型：期刊论文
| 作者 | Fang, Wenting; Ma, Zhongsen; Wang, Lei; Zhang, Yajie; Hu, Hualei |
| 刊名 | CATALYSTS
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:9 |
| 关键词 | Hierarchical Zeolites Pyrolysis Mesoporosity Deactivation Selectivity Conversion Catalyst Biomass Diesel Zsm-5 |
| 英文摘要 | The revealing mechanism of side reactions is crucial for obtaining theoretical yield in industrialization when 2,5-bis(methoxymethyl)furan (BMMF) yield is above 95%. By-products catalyzed by the conventional ZSM-5 (C-ZSM-5) and hierarchical porous ZSM-5 (HP-ZSM-5) catalytic systems were different, and some key by-products were identified. Thus, possible pathways were proposed, which helps to further improve BMMF selectivity. Additionally, HP-ZSM-5 exhibited quicker reaction rate, higher BMMF yield and selectivity, and slower deactivation process. The relatively weak acidity of HP-ZSM-5 suppresses the ring-opening reaction and subsequent side reactions, and introduction of mesopores improves mass transport and slightly increases hydration of 2,5-bis(hydroxymethyl)furan (BHMF). |
| 学科主题 | Science & Technology - Other Topics |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17213]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Fang, Wenting,Ma, Zhongsen,Wang, Lei,et al. Two Possible Side Reaction Pathways during Furanic Etherification[J]. CATALYSTS,2018,8(9). |
| APA | Fang, Wenting,Ma, Zhongsen,Wang, Lei,Zhang, Yajie,&Hu, Hualei.(2018).Two Possible Side Reaction Pathways during Furanic Etherification.CATALYSTS,8(9). |
| MLA | Fang, Wenting,et al."Two Possible Side Reaction Pathways during Furanic Etherification".CATALYSTS 8.9(2018). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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