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Interphase degradation of three-dimensional Cf/SiC–ZrC–ZrB2composites fabricated via reactive melt infiltration

文献类型：期刊论文

作者Chen, Xiaowu1,2,3; Feng, Qian4; Gao, Le1,2; Zhang, Xiangyu1,2; Dong, Shaoming1,2; Wang, Jingxiao1,2; Zhong, Qiang1,2,3; Kan, Yanmei1,2; Ni, Dewei1,2
刊名Journal of the American Ceramic Society
出版日期2017
卷号100期号:10页码:4816-4826
ISSN号00027820
DOI10.1111/jace.14983
英文摘要Layer-structured interphase, existing between carbon fiber and ultrahigh-temperature ceramics (UHTCs) matrix, is an indispensable component for carbon fiber reinforced UHTCs matrix composites (Cf/UHTCs). For Cf/UHTCs fabricated by reactive melt infiltration (RMI), the interphase inevitably suffers degradation due to the interaction with the reactive melt. Here, Cf/SiC–ZrC–ZrB2composite was fabricated by reactive infiltration of ZrSi2melt into sol-gel prepared Cf/B4C–C preform. (PyC–SiC)2interphase was deposited on the fiber to investigate the degradation mechanism under ZrSi2melt. It was revealed that the degraded interphase exhibited typical features of Zr aggregation and SiC residuals. Moreover, the Zr species diffused across the interphase and formed nanosized ZrC phase inside the fiber. A hybrid mechanisms of chemical reaction and physical melting were proposed to reveal the degradation mechanism according to characterization results and heat conduction calculations. Based on the degradation mechanism, a potential solution to mitigate interphase degradation is also put forward. © 2017 The American Ceramic Society
源URL[http://ir.sic.ac.cn/handle/331005/25757]  
专题中国科学院上海硅酸盐研究所
作者单位1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, China;
2.Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, China;
3.University of Chinese Academy of Sciences, Beijing, China;
4.Analysis and Testing Center, Donghua University, Shanghai, China
推荐引用方式
GB/T 7714		 Chen, Xiaowu,Feng, Qian,Gao, Le,et al. Interphase degradation of three-dimensional Cf/SiC–ZrC–ZrB2composites fabricated via reactive melt infiltration[J]. Journal of the American Ceramic Society,2017,100(10):4816-4826.
APA Chen, Xiaowu.,Feng, Qian.,Gao, Le.,Zhang, Xiangyu.,Dong, Shaoming.,...&Ni, Dewei.(2017).Interphase degradation of three-dimensional Cf/SiC–ZrC–ZrB2composites fabricated via reactive melt infiltration.Journal of the American Ceramic Society,100(10),4816-4826.
MLA Chen, Xiaowu,et al."Interphase degradation of three-dimensional Cf/SiC–ZrC–ZrB2composites fabricated via reactive melt infiltration".Journal of the American Ceramic Society 100.10(2017):4816-4826.

入库方式： OAI收割

来源：上海硅酸盐研究所

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