Complexation of manganese with glutarimidedioxime: implication for extraction uranium from seawater
文献类型：期刊论文
| 作者 | Xie, Xiang1; Tian, Yin2; Qin, Zhen3; Yu, Qianhong1; Wei, Hongyuan1; Wang, Dongqi4,5; Li, Xingliang1; Wang, Xiaolin1,3 |
| 刊名 | Scientific reports
 |
| 出版日期 | 2017-03-07 |
| 卷号 | 7页码:9 |
| ISSN号 | 2045-2322 |
| DOI | 10.1038/srep43503 |
| 通讯作者 | Li, xingliang(xingliang@caep.cn) ; Wang, xiaolin(xlwang@caep.cn) |
| 英文摘要 | The molecule of glutaroimidedioxime, a cyclic imidedioxime moiety that can form during the synthesis of the poly(amidoxime) sorbent and is reputedly responsible for the extraction of uranium from seawater. complexation of manganese (ii) with glutarimidedioxime in aqueous solutions was investigated with potentiometry, calorimetry, esi-mass spectrometry, electrochemical measurements and quantum chemical calculations. results show that complexation reactions of manganese with glutarimidedioxime are both enthalpy and entropy driven processes, implying that the sorption of manganese on the glutarimidedioxime-functionalized sorbent would be enhanced at higher temperatures. complex formation of manganese with glutarimidedioxime can assist redox of mn( ii/iii). there are about similar to 15% of equilibrium manganese complex with the ligand in seawater ph(8.3), indicating that manganese could compete to some degree with uranium for sorption sites. |
| WOS关键词 | CHEMICAL SPECIATION ; GAS-PHASE ; ENERGIES ; COORDINATION ; CAPTURE ; URANYL ; MODEL ; IONS ; FUNCTIONALIZATION ; SEQUESTRATION |
| WOS研究方向 | Science & Technology - Other Topics |
| WOS类目 | Multidisciplinary Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000395634500001 |
| 出版者 | NATURE PUBLISHING GROUP |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2176680 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Li, Xingliang; Wang, Xiaolin |
| 作者单位 | 1.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621999, Sichuan, Peoples R China 2.Southwestern Inst Phys, Chengdu 610041, Sichuan, Peoples R China 3.China Acad Engn Phys, Inst Mat, Mianyang 621900, Peoples R China 4.Chinese Acad Sci, CAS Key Lab Nucl Radiat & Nucl Energy Tech, Beijing 100049, Peoples R China 5.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Xiang,Tian, Yin,Qin, Zhen,et al. Complexation of manganese with glutarimidedioxime: implication for extraction uranium from seawater[J]. Scientific reports,2017,7:9. |
| APA | Xie, Xiang.,Tian, Yin.,Qin, Zhen.,Yu, Qianhong.,Wei, Hongyuan.,...&Wang, Xiaolin.(2017).Complexation of manganese with glutarimidedioxime: implication for extraction uranium from seawater.Scientific reports,7,9. |
| MLA | Xie, Xiang,et al."Complexation of manganese with glutarimidedioxime: implication for extraction uranium from seawater".Scientific reports 7(2017):9. |
入库方式： iSwitch采集
来源：高能物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。