Highly wettable and metallic nife-phosphate/phosphide catalyst synthesized by plasma for highly efficient oxygen evolution reaction
文献类型：期刊论文
| 作者 | Zhang, Qixing1; Li, Tiantian1,2; Liang, Junhui1; Wang, Ning1; Kong, Xiangbin1; Wang, Jiaou3; Qian, Haijie3; Zhou, Yurong4; Liu, Fengzhen4; Wei, Changchun1 |
| 刊名 | Journal of materials chemistry a
 |
| 出版日期 | 2018-05-07 |
| 卷号 | 6期号:17页码:7509-7516 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta01334a |
| 通讯作者 | Zhang, xiaodan(xdzhang@nankai.edu.cn) |
| 英文摘要 | Many catalysts exhibit a high overpotential with a current density of 10 ma cm(-2) for the oxygen evolution reaction (oer). high conductivity, wettability and active sites play key roles for a highly efficient oer catalyst. here, we report a nife foam starting material treated with a two-step process using plasma-enhanced chemical vapor deposition (pecvd) in the presence of ph3, co2 and h-2, to form phosphate (pi) and phosphide (p) groups on the foam, and forming nifepi/p. the self-supported material combines conductivity, wettability with active sites, and is used directly as a working electrode for excellent oxygen evolution in alkaline solutions. significantly, the strong synergistic effect between the phosphate and phosphide lead to a change in the surrounding electronic environment of metal ions that contributes to the increase in active sites, while improving the wettability and metallic nature of the catalyst, both of these result in an enhanced oer performance. this new material and design strategy appear to represent an intriguing advance that is likely to be of considerable interest to other researchers in the field. |
| WOS关键词 | X-RAY-ABSORPTION ; WATER OXIDATION CATALYSTS ; COBALT-PHOSPHATE ; IN-SITU ; PHOTOELECTRON-SPECTROSCOPY ; HYDROGEN-EVOLUTION ; ENERGY-CONVERSION ; LOW-TEMPERATURE ; PHOSPHIDES ; FE |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| WOS类目 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000431621700022 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177603 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Zhang, Xiaodan |
| 作者单位 | 1.Nankai Univ, Key Lab Photoelect Thin Film Devices & Technol Ti, Collaborat Innovat Ctr Chem Sci & Engn,Key Lab Op, Minist Educ,Inst Photoelect Thin Film Devices & T, Tianjin 300071, Peoples R China 2.Inner Mongolia Univ, Key Lab Semicond Photovolta Technol Univ Inner Mo, Sch Phys Sci & Technol, Hohhot 010021, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Qixing,Li, Tiantian,Liang, Junhui,et al. Highly wettable and metallic nife-phosphate/phosphide catalyst synthesized by plasma for highly efficient oxygen evolution reaction[J]. Journal of materials chemistry a,2018,6(17):7509-7516. |
| APA | Zhang, Qixing.,Li, Tiantian.,Liang, Junhui.,Wang, Ning.,Kong, Xiangbin.,...&Zhang, Xiaodan.(2018).Highly wettable and metallic nife-phosphate/phosphide catalyst synthesized by plasma for highly efficient oxygen evolution reaction.Journal of materials chemistry a,6(17),7509-7516. |
| MLA | Zhang, Qixing,et al."Highly wettable and metallic nife-phosphate/phosphide catalyst synthesized by plasma for highly efficient oxygen evolution reaction".Journal of materials chemistry a 6.17(2018):7509-7516. |
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