Organocopper(iii) compounds with well-defined structures undergo reductive elimination to form c-c or c-heteroatom bonds
文献类型：期刊论文
| 作者 | Liu, Liang; Xi, Zhenfeng |
| 刊名 | Chinese journal of chemistry
 |
| 出版日期 | 2018-12-01 |
| 卷号 | 36期号:12页码:1213-1221 |
| 关键词 | Structure elucidation Copper Reactive intermediate Organocopper(iii) Organocuprate(iii) Reductive elimination |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201800365 |
| 通讯作者 | Liu, liang(liang.liu@pku.edu.cn) ; Xi, zhenfeng(zfxi@pku.edu.cn) |
| 英文摘要 | Reductive elimination around cu(iii) atom arises an increasing attention, since this organometallic pathway has been often proposed in a range of cu-based reactions. however, due to limited organocopper(iii) compounds with well-defined structures, this elementary reaction still remains an extremely challenging issue. in this review, structurally well-defined organocopper(iii) compounds are mainly divided into three classes based on their ligands: perfluoromethyl cu(iii) compounds, macrocyclic ligand-based aryl-cu(iii) compounds, and spiro organocopper(iii) compounds chelated by bidentate ligands. the majority of organocopper(iii) compounds display the typical square planar geometry. there also exist a few penta-coordinated organocopper(iii) complexes, which share a weak apical cu-l bond. in order to form a cis cu(iii)-c and cu(iii)-nu bonding geometry required for reductive elimination, the re-arrangement of coordination modes around tetra-coordinated cu(iii) atoms is necessary. for the aryl-cu(iii) cationic complexes with one cu(iii)-c bond, the re-arrangement is triggered by the coordination of the fifth ligand (solvent or nucleophiles), while for the tetra-carbon-coordinated organocuprate(iii) compounds, the process might be realized via the cleavage of one cu(iii)-c bond by attack of electrophiles. stoichiometric and catalytic reactions involving well-defined organocopper(iii) compounds to form c-c or c-heteroatom bonds are discussed to support their intermediacy. |
| WOS关键词 | TRANSITION-METAL-COMPLEXES ; CROSS-COUPLING REACTIONS ; N-CONFUSED PORPHYRINS ; RAPID INJECTION NMR ; X-RAY-STRUCTURE ; H BOND ; TRIFLUOROMETHYL COMPLEXES ; CONJUGATE ADDITION ; CATALYTIC CYCLE ; COPPER(III) INTERMEDIATE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000450017200020 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373099 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Liu, Liang; Xi, Zhenfeng |
| 作者单位 | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Liang,Xi, Zhenfeng. Organocopper(iii) compounds with well-defined structures undergo reductive elimination to form c-c or c-heteroatom bonds[J]. Chinese journal of chemistry,2018,36(12):1213-1221. |
| APA | Liu, Liang,&Xi, Zhenfeng.(2018).Organocopper(iii) compounds with well-defined structures undergo reductive elimination to form c-c or c-heteroatom bonds.Chinese journal of chemistry,36(12),1213-1221. |
| MLA | Liu, Liang,et al."Organocopper(iii) compounds with well-defined structures undergo reductive elimination to form c-c or c-heteroatom bonds".Chinese journal of chemistry 36.12(2018):1213-1221. |
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来源：大连化学物理研究所
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