Effects of ag on morphology and catalytic performance of iron catalysts for fischer-tropsch synthesis
文献类型：期刊论文
| 作者 | Zhang, Yulan1,2; Ding, Mingyue1; Ma, Longlong1; Wang, Tiejun1; Li, Xinjun1 |
| 刊名 | Rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:72页码:58727-58733 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c5ra10105k |
| 通讯作者 | Wang, tiejun(wangtj@ms.giec.ac.cn) |
| 英文摘要 | Fe3o4 nanoparticles with pore size of 12.4 nm were synthesized and employed as catalyst for fischer-tropsch (ft) synthesis. the as-prepared fe3o4 catalyst achieved a co conversion of 98.3% while yielding higher than 50 wt% gasoline range (c-5-c-11) hydrocarbons after ft reaction for 48 h. furthermore, highly activated ag-doped composites were designed through a one-pot solvothermal method, and then porous core/shell materials were obtained. interestingly, active metal oxide (fe3o4) nanoparticles were interspersed on the surface of the ag promoter. importantly, pores could enhance the dispersion of metal particles and facilitate heat and mass transfer. the addition of ag promoter decreased the selectivity to ch4 and enhanced the yield of c-2-c-4 olefins. in particular, 0.8ag/fe3o4 displayed high co conversion (96.4%) and optimum selectivity to c-2-c-4 olefins (28.3 wt%) while yielding a low selectivity to ch4 (12.1 wt%), as well as a good selectivity to c-5-c-11. more importantly, 0.8ag/ fe3o4 showed the highest catalytic activity (>1.6 x 10(-4) mol(co) g(fe)(-1) s(-1)) and the best total hydrocarbon yield (5.25 x 10(-3) g(hc) g(fe)(-1) s(-1)). |
| WOS关键词 | ENHANCED PHOTOCATALYTIC ACTIVITY ; MICROSPHERES ; SPHERES ; IRRADIATION ; HOLLOW |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000357798400072 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374056 |
| 专题 | 物理研究所 |
| 通讯作者 | Wang, Tiejun |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yulan,Ding, Mingyue,Ma, Longlong,et al. Effects of ag on morphology and catalytic performance of iron catalysts for fischer-tropsch synthesis[J]. Rsc advances,2015,5(72):58727-58733. |
| APA | Zhang, Yulan,Ding, Mingyue,Ma, Longlong,Wang, Tiejun,&Li, Xinjun.(2015).Effects of ag on morphology and catalytic performance of iron catalysts for fischer-tropsch synthesis.Rsc advances,5(72),58727-58733. |
| MLA | Zhang, Yulan,et al."Effects of ag on morphology and catalytic performance of iron catalysts for fischer-tropsch synthesis".Rsc advances 5.72(2015):58727-58733. |
入库方式： iSwitch采集
来源：物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。