Nitrogen, iron-codoped mesoporous carbon with bimodal-pores as an efficient catalyst for the oxygen reduction reaction
文献类型：期刊论文
| 作者 | Xiao, Yao1,2; Ge, Junjie1,2; Xiao, Meiling1,2; Fateev, Vladimir3; Liu, Changpeng1,2; Xing, Wei1,2 |
| 刊名 | Electrochimica acta
 |
| 出版日期 | 2016-08-10 |
| 卷号 | 209页码:551-556 |
| 关键词 | Oxygen reduction reaction Nitrogen, iron-codoped carbon Ordered mesopore Triconstituent co-assembly |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2016.05.121 |
| 通讯作者 | Xing, wei(xingwei@ciac.ac.cn) |
| 英文摘要 | Nitrogen, iron-codoped ordered mesoporous carbon (nfe-omc) with bimodal-pores and extremely high bet area was fabricated and investigated as non-platinum catalysts for oxygen reduction reaction (orr). the catalysts show significantly enhanced electrocatalytic activity for orr in comparison to the doped commercial carbon black. a 4-electron process was shown in domination of the orr, indicating the direct reduction of o-2 to h2o. moreover, the stability of the catalyst was comparable to the state-of-the-art pt catalyst, which renders it a promising replacement for pt. the increase in activity was ascribed to the increase in active site density and more importantly, the increase in activity per active site, which is due to the advanced pore structure of omcs and the possible desolvation process of o-2 in the micropores. (c) 2016 elsevier ltd. all rights reserved. |
| WOS关键词 | ELECTROLYTE FUEL-CELLS ; METHANOL ELECTROOXIDATION ; ELECTROCATALYTIC ACTIVITY ; ACTIVE-SITES ; BLACK ; PYROLYSIS ; KINETICS ; SUPPORTS ; ACID |
| WOS研究方向 | Electrochemistry |
| WOS类目 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000379504600061 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374739 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xing, Wei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, 5625 Renmin St, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Kurchatov Inst, Natl Res Ctr, Pl Kurchatova 1, Moscow 123182, Russia |
| 推荐引用方式 GB/T 7714 | Xiao, Yao,Ge, Junjie,Xiao, Meiling,et al. Nitrogen, iron-codoped mesoporous carbon with bimodal-pores as an efficient catalyst for the oxygen reduction reaction[J]. Electrochimica acta,2016,209:551-556. |
| APA | Xiao, Yao,Ge, Junjie,Xiao, Meiling,Fateev, Vladimir,Liu, Changpeng,&Xing, Wei.(2016).Nitrogen, iron-codoped mesoporous carbon with bimodal-pores as an efficient catalyst for the oxygen reduction reaction.Electrochimica acta,209,551-556. |
| MLA | Xiao, Yao,et al."Nitrogen, iron-codoped mesoporous carbon with bimodal-pores as an efficient catalyst for the oxygen reduction reaction".Electrochimica acta 209(2016):551-556. |
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来源：中国科学院大学
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