Gold-catalyzed cyclization of 1,6-diynyl dithioacetals via 1,7-carbene transfer and aromatic c-h functionalization
文献类型：期刊论文
| 作者 | Xu, Wei; Chen, Ming; Sun, Ning; Liu, Yuanhong |
| 刊名 | Chemical communications
 |
| 出版日期 | 2016 |
| 卷号 | 52期号:73页码:11000-11003 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c6cc05302e |
| 通讯作者 | Liu, yuanhong(yhliu@sioc.ac.cn) |
| 英文摘要 | A gold-catalyzed cyclization of 1,6-diynyl dithioacetals has been developed, which provides an attractive route to diverse-substituted benzo[a]fluorene derivatives. the reaction is initiated through 1,2-sulfur migration of a propargyl dithioacetal moiety to generate a vinyl gold carbene, which is followed by carbene transfer to the remaining alkyne and aromatic substitution to furnish the fused products in generally good to high yields. |
| WOS关键词 | SUBSTITUTED ALPHA-DIAZOACETOPHENONES ; CARBENOID MEDIATED CYCLIZATIONS ; CARBONATES ; FACILE ; ESTERS ; CYCLOISOMERIZATION ; CYCLOADDITION ; INSERTION ; CASCADES ; MOIETY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000382674000015 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375295 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Yuanhong |
| 作者单位 | Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Wei,Chen, Ming,Sun, Ning,et al. Gold-catalyzed cyclization of 1,6-diynyl dithioacetals via 1,7-carbene transfer and aromatic c-h functionalization[J]. Chemical communications,2016,52(73):11000-11003. |
| APA | Xu, Wei,Chen, Ming,Sun, Ning,&Liu, Yuanhong.(2016).Gold-catalyzed cyclization of 1,6-diynyl dithioacetals via 1,7-carbene transfer and aromatic c-h functionalization.Chemical communications,52(73),11000-11003. |
| MLA | Xu, Wei,et al."Gold-catalyzed cyclization of 1,6-diynyl dithioacetals via 1,7-carbene transfer and aromatic c-h functionalization".Chemical communications 52.73(2016):11000-11003. |
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来源：中国科学院大学
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