Synthesis of metal organic framework (mof-5) with high selectivity for co2/n-2 separation in flue gas by maximum water concentration approach
文献类型：期刊论文
| 作者 | Jiang, Ning1,2; Deng, Zhiyong1,2; Liu, Shaoying1,2; Tang, Congming3; Wang, Gongying1,2 |
| 刊名 | Korean journal of chemical engineering
 |
| 出版日期 | 2016-09-01 |
| 卷号 | 33期号:9页码:2747-2755 |
| 关键词 | Metal organic framework-5 (mof-5) Water Co2 Adsorption Separation |
| ISSN号 | 0256-1115 |
| DOI | 10.1007/s11814-016-0092-8 |
| 通讯作者 | Deng, zhiyong(zhiyongdeng@cioc.ac.cn) ; Wang, gongying(gywang@cioc.ac.cn) |
| 英文摘要 | Water plays a crucial role in the synthesis mechanism of metal organic framework-5 (mof-5). synthesized mof-5 with good phase structure and large specific surface area is largely determined by an important synthesis factor: the total water concentration of the initial synthesis solution (c (tw) ). an understanding of the effects of different and high c (tw) on the synthesis of mof-5 and the investigation of the maximum c (tw) suitable for the synthesis of mof-5 are important to guide the synthesis of mof-5. through the research of the maximum c (tw) , a favorable synthetic approach was established which could realize the synthesis of mof-5 with fine performance on co2 adsorption and separation. the research results show that the maximum c (tw) could be as high as 1,440mmol/l, and synthesized mof-5 still has a good phase structure and a large specific surface area of 2,136m(2)/g (bet). synthesized mof-5 by the maximum c (tw) exhibits a high co2 adsorption capacity of 2.5mmol/g and a low n-2 adsorption capacity of 0.2mmol/g at 298 k and 100 kpa. more importantly, synthesized mof-5 by the maximum c (tw) exhibits a high selectivity for co2/n-2 of 18-22 at 298 k and 20-130 kpa in simulated flue gas. |
| WOS关键词 | CARBON-DIOXIDE ; ACTIVATED CARBON ; FUNCTIONAL-GROUPS ; ADSORPTION ; CO2 ; PRESSURES ; STORAGE ; DESIGN ; N-2 ; STABILITY |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Multidisciplinary ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000382675200029 |
| 出版者 | KOREAN INSTITUTE CHEMICAL ENGINEERS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2375660 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Deng, Zhiyong; Wang, Gongying |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu Organ Chem Co Ltd, Chengdu 610041, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.China West Normal Univ, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong 637002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Ning,Deng, Zhiyong,Liu, Shaoying,et al. Synthesis of metal organic framework (mof-5) with high selectivity for co2/n-2 separation in flue gas by maximum water concentration approach[J]. Korean journal of chemical engineering,2016,33(9):2747-2755. |
| APA | Jiang, Ning,Deng, Zhiyong,Liu, Shaoying,Tang, Congming,&Wang, Gongying.(2016).Synthesis of metal organic framework (mof-5) with high selectivity for co2/n-2 separation in flue gas by maximum water concentration approach.Korean journal of chemical engineering,33(9),2747-2755. |
| MLA | Jiang, Ning,et al."Synthesis of metal organic framework (mof-5) with high selectivity for co2/n-2 separation in flue gas by maximum water concentration approach".Korean journal of chemical engineering 33.9(2016):2747-2755. |
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来源：中国科学院大学
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