Dual-bed catalyst system for the direct synthesis of high density aviation fuel with cyclopentanone from lignocellulose
文献类型：期刊论文
| 作者 | Sheng, Xueru1,2; Li, Guangyi1; Wang, Wentao1; Cong, Yu1; Wang, Xiaodong1; Huber, George W.3; Li, Ning1,4; Wang, Aiqin1,4; Zhang, Tao1,4 |
| 刊名 | Aiche journal
 |
| 出版日期 | 2016-08-01 |
| 卷号 | 62期号:8页码:2754-2761 |
| 关键词 | Lignocellulose High density aviation fuel Aldol condensation Hydrodeoxygenation Dual-bed continuous flow reactor |
| ISSN号 | 0001-1541 |
| DOI | 10.1002/aic.15248 |
| 通讯作者 | Li, ning(lining@dicp.ac.cn) ; Zhang, tao(taozhang@dicp.ac.cn) |
| 英文摘要 | In this article, we demonstrated an integrated process for the direct production of tri(cyclopentane) with cyclopentanone which can be obtained from lignocellulose. the reaction was carried out in a dual-bed continuous flow reactor. in the first bed, cyclopentanone was selectively converted to 2,5-dicyclopentylcyclopentanol over the pd-mgal-ht (hydrotalcite) catalyst. under solvent-free and mild conditions (443 k, 0.1 mpa h-2), high carbon yield (81.2%) of 2,5-dicyclopentylcyclopentanol was achieved. subsequently, the 2,5-dicyclopentylcyclopentanol was further hydrodeoxygenated to tri(cyclopentane) in the second bed. among the investigated catalysts, the ni-h beta-dp prepared by deposition-precipitation (dp) method exhibited the highest activity for the hydrodeoxygenation step. by using pd-mgal-ht as the first bed catalyst and ni-hbdp as the second bed catalyst, tri(cyclopentane) was directly produced at high carbon yield (80.0%) with cyclopentanone as feedstock. this polycycloalkane has high density (0.91 kg/l) and can be used as additive to improve the density and volumetric heating value of bio-jet fuel. (c) 2016 american institute of chemical engineers |
| WOS关键词 | HIGH-QUALITY DIESEL ; SELECTIVE HYDROGENATION ; TRANSPORTATION FUELS ; BIMETALLIC CATALYSTS ; BIODIESEL PRODUCTION ; SINGLE-REACTOR ; LIQUID ALKANES ; RANGE ALKANES ; BIOMASS ; CONVERSION |
| WOS研究方向 | Engineering |
| WOS类目 | Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000382986000014 |
| 出版者 | WILEY-BLACKWELL |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2376230 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Ning; Zhang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China 3.Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA 4.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sheng, Xueru,Li, Guangyi,Wang, Wentao,et al. Dual-bed catalyst system for the direct synthesis of high density aviation fuel with cyclopentanone from lignocellulose[J]. Aiche journal,2016,62(8):2754-2761. |
| APA | Sheng, Xueru.,Li, Guangyi.,Wang, Wentao.,Cong, Yu.,Wang, Xiaodong.,...&Zhang, Tao.(2016).Dual-bed catalyst system for the direct synthesis of high density aviation fuel with cyclopentanone from lignocellulose.Aiche journal,62(8),2754-2761. |
| MLA | Sheng, Xueru,et al."Dual-bed catalyst system for the direct synthesis of high density aviation fuel with cyclopentanone from lignocellulose".Aiche journal 62.8(2016):2754-2761. |
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来源：中国科学院大学
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