中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The study on the stability constant and species distribution of eu(iii) and tb(iii) complexes with bdbph

文献类型:期刊论文

作者Shangguan, GQ; Zhu, J; Wang, N; Ni, JZ
刊名Chinese chemical letters
出版日期2005-12-01
卷号16期号:12页码:1671-1674
关键词Bdbph Eu(iii) Tb(iii) Stability constant Species distribution
ISSN号1001-8417
通讯作者Shangguan, gq(gqshangguan@sohu.com)
英文摘要The stability constants and species distributions of complexes of two lanthanide ions, eu(iii) and tb(iii), with a macrocyclic ligand, bdbph, in 1:1 and 2:1system, were determined potentiometrically at 25.0 degrees c and i=0.100 mol l-1. the two metal ions could form deprotonated mono- or dinuclear complexes with bdbph after the first two protons of the ligand completely neutralized. at higher ph values, eu(iii) could not form hydroxy complexes with bdbph, while tb(iii) could form hydroxy complexes in the type of m2l(oh), m2l(oh)(2), and m2l(oh)(3).
WOS关键词HYDROLYSIS ; LIGAND ; DNA
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
WOS记录号WOS:000234002100031
出版者CHINESE CHEMICAL SOCIETY
URI标识http://www.irgrid.ac.cn/handle/1471x/2377054
专题中国科学院大学
通讯作者Shangguan, GQ
作者单位1.Jining Med Coll, Dept Chem, Jining 272013, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Shangguan, GQ,Zhu, J,Wang, N,et al. The study on the stability constant and species distribution of eu(iii) and tb(iii) complexes with bdbph[J]. Chinese chemical letters,2005,16(12):1671-1674.
APA Shangguan, GQ,Zhu, J,Wang, N,&Ni, JZ.(2005).The study on the stability constant and species distribution of eu(iii) and tb(iii) complexes with bdbph.Chinese chemical letters,16(12),1671-1674.
MLA Shangguan, GQ,et al."The study on the stability constant and species distribution of eu(iii) and tb(iii) complexes with bdbph".Chinese chemical letters 16.12(2005):1671-1674.

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来源:中国科学院大学

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