Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene
文献类型：期刊论文
| 作者 | Chen, JL; Zhang, LY; Shi, LX; Ye, HY; Chen, ZN |
| 刊名 | Inorganica chimica acta
 |
| 出版日期 | 2005-03-01 |
| 卷号 | 358期号:4页码:859-864 |
| 关键词 | Bis(diphenylphosphino)anthracene Bis(diphenylphosphino)ferrocene Electronic communication P ligand Redox properties Ruthenium |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2004.10.013 |
| 通讯作者 | Chen, zn() |
| 英文摘要 | Diphosphine-bridged dimers of oxo-centered triruthenium-acetate cluster units, i.e., [{ru3o(oac)(6)(py)(2)}(2)(dppan)](pf6)(2) (2) and [{ru3o(oac)(6)(py)(2)}(2)(dppf)](pf6)(2) (3) were prepared by reaction of 2.3 equivalent [ru3o(oac)(6)(py)(2)(ch3oh)](pf6) with 9,10-bis(diphenylphosphino)anthracene (dppan) or 1,1'-bis(diphenylphosphino)ferrocene (dppf), respectively. apparent redox wave splitting is observed in complex 2, revealing the presence of electronic communication between two triruthenium units mediated through bridging dppan. the complexes were characterized by elemental analysis, ir, uv-vis, p-31 nmr, and es-ms spectroscopies, and cyclic and differential-pulse voltammetry. the crystal structure of complex 3 was determined by x-ray crystallography. (c) 2004 elsevier b.v. all rights reserved. |
| WOS关键词 | INTRAMOLECULAR ELECTRON-TRANSFER ; TRINUCLEAR RUTHENIUM COMPLEX ; VIBRATIONAL TIME-SCALE ; MIXED-VALENCE STATE ; ORGANOMETALLIC COMPLEXES ; REVERSIBLE MULTISTEP ; ISOCYANIDE LIGANDS ; ACETATE CLUSTERS ; METAL-COMPLEXES ; BEHAVIOR |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000227507800001 |
| 出版者 | ELSEVIER SCIENCE SA |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377166 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, ZN |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, JL,Zhang, LY,Shi, LX,et al. Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene[J]. Inorganica chimica acta,2005,358(4):859-864. |
| APA | Chen, JL,Zhang, LY,Shi, LX,Ye, HY,&Chen, ZN.(2005).Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene.Inorganica chimica acta,358(4),859-864. |
| MLA | Chen, JL,et al."Preparation, characterization and redox chemistry of oxo-centered triruthenium dimers linked by bis(diphenylphosphino)anthracene and -ferrocene".Inorganica chimica acta 358.4(2005):859-864. |
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来源：中国科学院大学
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