Tetramethylguanidine as an inexpensive and efficient ligand for the palladium-catalyzed heck reaction
文献类型：期刊论文
| 作者 | Li, SH; Xie, HB; Zhang, SB; Lin, YJ; Xu, JN; Cao, JG |
| 刊名 | Synlett
 |
| 出版日期 | 2005-08-01 |
| 期号 | 12页码:1885-1888 |
| 关键词 | Tetramethylguanidine Heck reaction Palladium Aryl halides Ligand |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-2005-871581 |
| 通讯作者 | Zhang, sb() |
| 英文摘要 | An inexpensive and efficient pd(oac)(2)/tetramethylguanidine (tmg) or pdcl2/tmg catalytic system has been developed for the heck reaction of an olefin with an aryl halide. the tons were up to 1000000 when iodobenzene was used as the substrate with butyl acrylate as the reactant. in addition, [pd(tmg)(4)]cl-2(h2o)(8), an air-stable compound, effectively promoted the heck reaction, which demonstrated that tmg acted as a ligand in this reaction system. |
| WOS关键词 | CARBON COUPLING REACTIONS ; HIGHLY EFFICIENT ; ARYL CHLORIDES ; PALLADACYCLE CATALYST ; PD(II) CATALYSTS ; IONIC LIQUIDS ; COMPLEXES ; PRECURSORS ; BROMIDES ; CHLOROARENES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000231028100012 |
| 出版者 | GEORG THIEME VERLAG KG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378331 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, SB |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Grad Sch, Changchun 130022, Peoples R China 2.Jilin Univ, Coll Chem, Changchun 130023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, SH,Xie, HB,Zhang, SB,et al. Tetramethylguanidine as an inexpensive and efficient ligand for the palladium-catalyzed heck reaction[J]. Synlett,2005(12):1885-1888. |
| APA | Li, SH,Xie, HB,Zhang, SB,Lin, YJ,Xu, JN,&Cao, JG.(2005).Tetramethylguanidine as an inexpensive and efficient ligand for the palladium-catalyzed heck reaction.Synlett(12),1885-1888. |
| MLA | Li, SH,et al."Tetramethylguanidine as an inexpensive and efficient ligand for the palladium-catalyzed heck reaction".Synlett .12(2005):1885-1888. |
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来源：中国科学院大学
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