Design of highly enantioselective organocatalysts based on molecular recognition
文献类型：期刊论文
| 作者 | Tang, Z; Cun, LF; Cui, X; Mi, AQ; Jiang, YZ; Gong, LZ |
| 刊名 | Organic letters
 |
| 出版日期 | 2006-03-30 |
| 卷号 | 8期号:7页码:1263-1266 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/ol0529391 |
| 通讯作者 | Gong, lz() |
| 英文摘要 | Various organocatalysts have been designed based on molecular recognition to catalyze the asymmetric direct aldol reaction of ketones with aryl and alkyl alpha-keto acids, affording beta-hydroxyl carboxylic acids with a tertiary stereogenic center with excellent enantioselectivities of up to 98% ee. a linear effect was observed for the reaction, demonstrating a single molecule of the catalyst involved in the catalysis. |
| WOS关键词 | DIRECT ALDOL REACTIONS ; CATALYTIC ASYMMETRIC ALDOL ; DICARBOXYLIC-ACIDS ; AMINO-ACID ; VERSATILE CATALYSTS ; ORGANIC-MOLECULES ; CARBOXYLIC-ACIDS ; CROWN-ETHERS ; PROLINE ; ALDEHYDES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000236397000003 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378509 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Gong, LZ |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Z,Cun, LF,Cui, X,et al. Design of highly enantioselective organocatalysts based on molecular recognition[J]. Organic letters,2006,8(7):1263-1266. |
| APA | Tang, Z,Cun, LF,Cui, X,Mi, AQ,Jiang, YZ,&Gong, LZ.(2006).Design of highly enantioselective organocatalysts based on molecular recognition.Organic letters,8(7),1263-1266. |
| MLA | Tang, Z,et al."Design of highly enantioselective organocatalysts based on molecular recognition".Organic letters 8.7(2006):1263-1266. |
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来源：中国科学院大学
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