Phosphate diester hydrolysis by dinuclear tb(iii) complexes with bdbph in second-order dependence
文献类型：期刊论文
| 作者 | Shangguan, GQ; Zhu, J; Wang, N; Ni, JZ |
| 刊名 | Chinese chemical letters
 |
| 出版日期 | 2006 |
| 卷号 | 17期号:1页码:89-92 |
| 关键词 | Tb(iii)-bdbph Phosphate diester Hydrolysis Rate constant |
| ISSN号 | 1001-8417 |
| 通讯作者 | Shangguan, gq(gqshangguan@sohu.com) |
| 英文摘要 | The kinetic study on the hydrolysis reaction of bis(4-nitrophenyl) phosphate (bnpp) catalyzed by tb-bdbph system(2:1) was carried out in 50% ethanol solution (ph 7.0-10.0) at 35 degrees c with 1=0.10nano(3). the second-order rate constant k(bnpp), 2.3x 10(-3) (mol(-1)l s-1), was determined. the dinuclear monohydroxo species, l-2tb-oh, is kinetically mainly active species. the hydrolysis rate of bnpp by the complex is increased almost 2.6 million-fold compared with the background hydroxide rate at the same condition. |
| WOS关键词 | LANTHANIDE COMPLEXES ; ALCOHOL-PENDANT ; DNA ; CATALYSIS ; CLEAVAGE ; ZINC(II) |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000235375200024 |
| 出版者 | CHINESE CHEMICAL SOCIETY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378980 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Shangguan, GQ |
| 作者单位 | 1.Jining Med Coll, Dept Chem, Jining 272013, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shangguan, GQ,Zhu, J,Wang, N,et al. Phosphate diester hydrolysis by dinuclear tb(iii) complexes with bdbph in second-order dependence[J]. Chinese chemical letters,2006,17(1):89-92. |
| APA | Shangguan, GQ,Zhu, J,Wang, N,&Ni, JZ.(2006).Phosphate diester hydrolysis by dinuclear tb(iii) complexes with bdbph in second-order dependence.Chinese chemical letters,17(1),89-92. |
| MLA | Shangguan, GQ,et al."Phosphate diester hydrolysis by dinuclear tb(iii) complexes with bdbph in second-order dependence".Chinese chemical letters 17.1(2006):89-92. |
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来源：中国科学院大学
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