Investigation of chiral recognition of 1,1 '-bi-2-naphthol enantiomers by heptakis-(2,6-di-o-methyl)-beta-cyclodextrin with electrospray mass spectrometry
文献类型：期刊论文
| 作者 | Yu Zhan; Yan Cun-Yu; Song Feng-Rui; Liu Zhi-Qiang; Liu Shu-Ying |
| 刊名 | Acta chimica sinica
 |
| 出版日期 | 2006-07-28 |
| 卷号 | 64期号:14页码:1507-1512 |
| 关键词 | Chiral recognition Cyclodextrin 1,1 '-bi-2-naphthol Electrospray ionization Noncovalent complex |
| ISSN号 | 0567-7351 |
| 通讯作者 | Yu zhan(yuzhan@163.com) |
| 英文摘要 | Chiral recognition of enantiomeric 1,1'-bi-2-naphthol enantiomers by beta- and heptakis-(2,6-di-o-methyl)-beta-cyclodextrins as chiral selectors was investigated by electrospray mass spectrometry. comparative research shows that both beta-cyclodextrin and heptakis-(2,6-di-o-methyl)-beta-cyclodextrin can form noncovalent complexes with 1,1'-bi-2-naphthol in gas phase. investigation of tandem mass spectrometric data displays that beta-cyclodextrin has little chiral recognition ability to the enantiomers but heptakis-(2,6-di-o-methyl)-beta-cyclodextrin has strong chiral recognition ability. our work also displays that mixing ratio of heptakis-(2,6-di-o-methyl)-beta-cyclodextrin to 1,1'-bi-2-naphthol and the collision induced disossiation energy have no effect on chiral recognition. |
| WOS关键词 | ACID INCLUSION COMPLEX ; GAS-PHASE ; AMINO-ACIDS ; CELLULOSE TRIS(5-FLUORO-2-METHYLPHENYLCARBAMATE) ; CRYSTAL-STRUCTURES ; BETA-CYCLODEXTRIN ; D,L-AMINO ACIDS ; EXCESS ; DERIVATIVES ; RESOLUTION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000239536400016 |
| 出版者 | SCIENCE CHINA PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379143 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yu Zhan |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Lab New Drug Res, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu Zhan,Yan Cun-Yu,Song Feng-Rui,et al. Investigation of chiral recognition of 1,1 '-bi-2-naphthol enantiomers by heptakis-(2,6-di-o-methyl)-beta-cyclodextrin with electrospray mass spectrometry[J]. Acta chimica sinica,2006,64(14):1507-1512. |
| APA | Yu Zhan,Yan Cun-Yu,Song Feng-Rui,Liu Zhi-Qiang,&Liu Shu-Ying.(2006).Investigation of chiral recognition of 1,1 '-bi-2-naphthol enantiomers by heptakis-(2,6-di-o-methyl)-beta-cyclodextrin with electrospray mass spectrometry.Acta chimica sinica,64(14),1507-1512. |
| MLA | Yu Zhan,et al."Investigation of chiral recognition of 1,1 '-bi-2-naphthol enantiomers by heptakis-(2,6-di-o-methyl)-beta-cyclodextrin with electrospray mass spectrometry".Acta chimica sinica 64.14(2006):1507-1512. |
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来源：中国科学院大学
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