Photochromism induced aggregate-monomer interconversion and fluorescence switch of porphyrin with spiropyran
文献类型：期刊论文
| 作者 | Li, Yuanyuan1,3; Fan, Meigong2; Zhang, Shuxiao1; Yao, Jiannian1 |
| 刊名 | Journal of physical organic chemistry
 |
| 出版日期 | 2007-11-01 |
| 卷号 | 20期号:11页码:884-887 |
| 关键词 | Photochromism Spiropyran Switch |
| ISSN号 | 0894-3230 |
| DOI | 10.1002/poc.1195 |
| 通讯作者 | Yao, jiannian(jnyao@iceas.ac.cn) |
| 英文摘要 | A photo-induced fluorescence switch based on a novel mechanism was provided by physically mixed tpps (tetra (4-phenylsulfonic acid) porphyrin) and sp (1-(beta-carboxyethyl)-3, 3-dimethyl-5'-nitrospiro (indoline-2, 2' [2h-1] benzopyran)). the ground state dipole moment of the open form (photomerocyanine, mc) is much larger than that of sp, thus it can induce the transformation of aggregated tpps to its monomer, which is confirmed by uv-vis absorption spectra, rls spectra, and fluorescence lifetime. while tpps aggregate has a fluorescence self-quenching phenomenon, its fluorescence was greatly enhanced after the formation of monomer. when the mixture was exposed to visible light, mc decayed back to sp, and consequently, tpps monomer aggregated again, which resulted in its fluorescence turn off. copyright (c) 2007 john wiley & sons, ltd. |
| WOS关键词 | RESONANCE LIGHT-SCATTERING ; ENERGY-TRANSFER ; SUPRAMOLECULAR ASSEMBLIES ; LINKED PORPHYRIN ; STORAGE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic ; Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000251947100013 |
| 出版者 | JOHN WILEY & SONS LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380532 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yao, Jiannian |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, BNLMS, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yuanyuan,Fan, Meigong,Zhang, Shuxiao,et al. Photochromism induced aggregate-monomer interconversion and fluorescence switch of porphyrin with spiropyran[J]. Journal of physical organic chemistry,2007,20(11):884-887. |
| APA | Li, Yuanyuan,Fan, Meigong,Zhang, Shuxiao,&Yao, Jiannian.(2007).Photochromism induced aggregate-monomer interconversion and fluorescence switch of porphyrin with spiropyran.Journal of physical organic chemistry,20(11),884-887. |
| MLA | Li, Yuanyuan,et al."Photochromism induced aggregate-monomer interconversion and fluorescence switch of porphyrin with spiropyran".Journal of physical organic chemistry 20.11(2007):884-887. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。