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Interaction between electrical double layers of soil colloids and fe/al oxides in suspensions

文献类型:期刊论文

作者Hou, Tao; Xu, Renkou; Tiwari, Diwakar; Zhao, Anzhen
刊名Journal of colloid and interface science
出版日期2007-06-15
卷号310期号:2页码:670-674
关键词Zeta potential Electrical double layer Interaction of diffuse layers Variable-charge soil Constant-charge soil Goethite Gamma-al2o3
ISSN号0021-9797
DOI10.1016/j.jcis.2007.02.035
通讯作者Xu, renkou(rkxu@issas.ac.cn)
英文摘要Phyllosilicates with net negative surface charge and fe/al oxides with net positive surface charge coexist in variable-charge soils, and the interaction between these oppositely charged particles affects the stability of mixed colloids, aggregation, and even the surface chemical properties of variable-charge soils. the interaction of the diffuse layers of electrical double layers between the negatively charged soil colloidal particles and the positively charged particles of goethite or gamma-al2o3 was investigated in this article through the comparison of zeta potentials between single-soil colloidal systems and binary systems containing soil colloids and fe/al oxides. the results showed that the presence of goethite and gamma-al2o3 increased the zeta potential of the binary system containing soil colloids and fe/al oxides, which clearly suggests the overlapping of the diffuse layers in soil colloids and fe/al oxides. the overlapping of the diffuse layers leads to a decrease in the effective negative charge density on soil colloid and thus causes a shift of ph-zeta potential curves toward the more positive-value side. the interaction of the electrical double layers is also related to the charge characteristics on the fe/al oxides: the higher the positive charge density on fe/al oxides, the stronger the interaction of the electrical double layers between the soil colloid particles and the fe/al oxides. (c) 2007 elsevier inc. all rights reserved.
WOS关键词VARIABLE CHARGE SUBSOILS ; ADSORPTION ; PARTICLE ; IONS
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
WOS记录号WOS:000246459700039
出版者ACADEMIC PRESS INC ELSEVIER SCIENCE
URI标识http://www.irgrid.ac.cn/handle/1471x/2381893
专题中国科学院大学
通讯作者Xu, Renkou
作者单位1.Chinese Acad Sci, Inst Soil Sci, State Key Lab Soil & Sustainable Agr, Nanjing, Peoples R China
2.Grad Univ, Chinese Acad Sci, Beijing 100039, Peoples R China
3.Mizoram Univ, Dept Chem, Aizawl 796001, India
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GB/T 7714
Hou, Tao,Xu, Renkou,Tiwari, Diwakar,et al. Interaction between electrical double layers of soil colloids and fe/al oxides in suspensions[J]. Journal of colloid and interface science,2007,310(2):670-674.
APA Hou, Tao,Xu, Renkou,Tiwari, Diwakar,&Zhao, Anzhen.(2007).Interaction between electrical double layers of soil colloids and fe/al oxides in suspensions.Journal of colloid and interface science,310(2),670-674.
MLA Hou, Tao,et al."Interaction between electrical double layers of soil colloids and fe/al oxides in suspensions".Journal of colloid and interface science 310.2(2007):670-674.

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