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The effect of annealing temperature on crystallization of poly(vinylidene fluoride) films prepared from poly(vinylidene fluoride)/amide solution

文献类型:期刊论文

作者Song Rui; Yang Debin; Xie Qiaoli; He Linghao; Liu Baofei
刊名Acta polymerica sinica
出版日期2007-02-01
期号2页码:144-147
关键词Polyvinylidene fluoride Crystallization Film thickness Ft-ir spectrum
ISSN号1000-3304
通讯作者Song rui()
英文摘要The crystallization of poly(vinylidene fluoride) (pvdf) films prepared from dimethylformamide (dmf) and dimethylacetamide ( dmac) solution and subsequently annealed at various temperature was studied by ft-ir and optical microscope. the results indicate that the crystallization of pvdf film depends on solvent, annealing temperature and film thickness. for all samples the content of beta phase, f (beta), decreases with elevating annealing temperature. when the annealing temperature is less than 90 degrees c the f(beta) of pvdf-dmf system is higher than that of pvdf-dmac system; however, at 90 similar to 160 degrees c, a reversed observation is obtained. for the two systems, interestingly, the f (beta) decreases drastically at the region of ca 90 degrees c and 80 degrees c, respectively. in addition, the crystallization of pvdf is also affected by film thickness, higher film thickness will make the spherulite more resolved.
WOS关键词TRANSFORMATION MECHANISMS ; POLYMER-FILMS ; PVDF FILMS ; DEFORMATION
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000244405600009
出版者SCIENCE PRESS
URI标识http://www.irgrid.ac.cn/handle/1471x/2381978
专题中国科学院大学
通讯作者Song Rui
作者单位1.Zhengzhou Univ Light Ind, Coll Chem Engn & Mat, Zhengzhou 450002, Peoples R China
2.Grad Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Song Rui,Yang Debin,Xie Qiaoli,et al. The effect of annealing temperature on crystallization of poly(vinylidene fluoride) films prepared from poly(vinylidene fluoride)/amide solution[J]. Acta polymerica sinica,2007(2):144-147.
APA Song Rui,Yang Debin,Xie Qiaoli,He Linghao,&Liu Baofei.(2007).The effect of annealing temperature on crystallization of poly(vinylidene fluoride) films prepared from poly(vinylidene fluoride)/amide solution.Acta polymerica sinica(2),144-147.
MLA Song Rui,et al."The effect of annealing temperature on crystallization of poly(vinylidene fluoride) films prepared from poly(vinylidene fluoride)/amide solution".Acta polymerica sinica .2(2007):144-147.

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来源:中国科学院大学

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