Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n)
文献类型：期刊论文
| 作者 | Wang Jian; Huang Mei-Hua; Liu Ping; Cheng Wen-Dan; Zhang Li-Mei |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:2页码:139-142 |
| 关键词 | Crystal structure Manganese complex Eight-membered ring One-dimensional chain |
| ISSN号 | 0254-5861 |
| 通讯作者 | Liu ping(pliu@fjirsm.ac.cn) |
| 英文摘要 | The title compound, [mn-2(.)(dinitrobenzoic acid)(4)(.)(1,10-phen)(2)](n), has a linear chain structure containing binuclear [mn2(.)(dinitrobenzoic acid)4(1,10-phen)2] repeat units. it crystallizes in the triclinic system, space group p (1) over bar with a = 7.9261(8), b = 12.1329(15), c = 14.847(2) angstrom, alpha = 103.845(5), beta = 101.424(5), gamma = 92.618(4), m-r = 657.37, v = 1352.3(2) angstrom(3), z = 2, d-c = 1.614 g/cm(3), f(000) = 666, mu = 0.567 min(-1), the final r = 0.0407 and wr = 0.1015 for 4081 observed reflections with i > 2 sigma(i). the mn atom is six-coordinated by two n and four o atoms, forming a slightly distorted octahedral geometry. all mn-o and mn-n bond distances range from 2.093(2) to 2.310(2) angstrom. two adjacent octahedral units are bridged together by two pairs of bi-monodentate carboxyl groups of different dinitrobenzoic acids to form an eight-membered ring with chair-typed configuration, thus generating a one-dimensional chain along the a axis. |
| WOS关键词 | BIOLOGICAL RELEVANCE |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000244505000002 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2383898 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu Ping |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Jian,Huang Mei-Hua,Liu Ping,et al. Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n)[J]. Chinese journal of structural chemistry,2007,26(2):139-142. |
| APA | Wang Jian,Huang Mei-Hua,Liu Ping,Cheng Wen-Dan,&Zhang Li-Mei.(2007).Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n).Chinese journal of structural chemistry,26(2),139-142. |
| MLA | Wang Jian,et al."Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n)".Chinese journal of structural chemistry 26.2(2007):139-142. |
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来源：中国科学院大学
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