中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of amphiphilic fluorinated copolymer and the formation of hollow nanotubes

文献类型:期刊论文

作者Xu, Shouping1,2; Liu, Weiqu1
刊名Colloids and surfaces a-physicochemical and engineering aspects
出版日期2008-09-01
卷号326期号:3页码:210-213
关键词Fluorinated Raft Aggregate Extraction
ISSN号0927-7757
DOI10.1016/j.colsurfa.2008.05.029
通讯作者Liu, weiqu(liuwq@gic.ac.cn)
英文摘要Amphiphilic fluorinated block copolymers are prepared via the two-step reversible addition-fragmentation chain transfer polymerization (raft), and micelles with well-defined core-shell morphology can be observed in the soap-free aqueous emulsion by transmission electron microscopy (tem). by adding a relatively excessive amount of initiator, free radical polymerization also happens, and a small amount of hydrophobic homopolymers are produced, which exist in the hydrophobic core. after extracting homopolymers in the core by adding a certain amount of benzotrifluoride into the diluted emulsion, drastic changes in the morphology and stability of fluorinated block copolymers aggregate were observed. first, cross-link and aggregating of the micelles was observed; second, by stirring for a further 50 min. hollow nanotubes can be produced. (c) 2008 elsevier b.v. all rights reserved.
WOS关键词BLOCK-COPOLYMERS ; ACID) ; MORPHOLOGIES ; COMPLEXES ; VESICLES ; PARTICLES
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
WOS记录号WOS:000259269600013
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2386576
专题中国科学院大学
通讯作者Liu, Weiqu
作者单位1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Xu, Shouping,Liu, Weiqu. Synthesis of amphiphilic fluorinated copolymer and the formation of hollow nanotubes[J]. Colloids and surfaces a-physicochemical and engineering aspects,2008,326(3):210-213.
APA Xu, Shouping,&Liu, Weiqu.(2008).Synthesis of amphiphilic fluorinated copolymer and the formation of hollow nanotubes.Colloids and surfaces a-physicochemical and engineering aspects,326(3),210-213.
MLA Xu, Shouping,et al."Synthesis of amphiphilic fluorinated copolymer and the formation of hollow nanotubes".Colloids and surfaces a-physicochemical and engineering aspects 326.3(2008):210-213.

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来源:中国科学院大学

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