Catalytic asymmetric diethylzinc addition to diphenylphosphionyl imines using chiral tert-butanesulfinylphosphine ligands
文献类型:期刊论文
作者 | Chen, Junmin1,2,3,4; Li, Dong1,2,3; Ma, Haifeng1,2; Cun, Linfeng1,2; Zhu, Jin1,2,3; Deng, Jingen1,2,3; Liao, Jian1,2,3 |
刊名 | Tetrahedron letters
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出版日期 | 2008-11-24 |
卷号 | 49期号:48页码:6921-6923 |
ISSN号 | 0040-4039 |
DOI | 10.1016/j.tetlet.2008.09.111 |
通讯作者 | Liao, jian(jliao10@cioc.ac.cn) |
英文摘要 | A class of novel chiral tert-butanesulfinylphosphine ligands were designed and synthesized by a concise two-step route with high yields. high activities and enantioselectivities (up to 94% ee) were achieved when using them in catalytic asymmetric diethylzinc addition to diphenylphosphinoyl imines. (c) 2008 elsevier ltd. all rights reserved. |
WOS关键词 | NUCLEOPHILIC-SUBSTITUTION REACTIONS ; ENANTIOSELECTIVE ADDITION ; DIORGANOZINC REAGENTS ; CONJUGATE ADDITION ; BIS(SULFINYL)IMIDOAMIDINE LIGANDS ; N-(DIPHENYLPHOSPHINOYL) IMINES ; ORGANOMETALLIC REAGENTS ; SULFOXIDE COMPLEXES ; ALLYLIC ALKYLATION ; C=N BONDS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
WOS记录号 | WOS:000260843500051 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2388006 |
专题 | 中国科学院大学 |
通讯作者 | Liao, Jian |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Junmin,Li, Dong,Ma, Haifeng,et al. Catalytic asymmetric diethylzinc addition to diphenylphosphionyl imines using chiral tert-butanesulfinylphosphine ligands[J]. Tetrahedron letters,2008,49(48):6921-6923. |
APA | Chen, Junmin.,Li, Dong.,Ma, Haifeng.,Cun, Linfeng.,Zhu, Jin.,...&Liao, Jian.(2008).Catalytic asymmetric diethylzinc addition to diphenylphosphionyl imines using chiral tert-butanesulfinylphosphine ligands.Tetrahedron letters,49(48),6921-6923. |
MLA | Chen, Junmin,et al."Catalytic asymmetric diethylzinc addition to diphenylphosphionyl imines using chiral tert-butanesulfinylphosphine ligands".Tetrahedron letters 49.48(2008):6921-6923. |
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来源:中国科学院大学
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