Collinear Velocity-map Photoelectron Imaging Spectrometer for Cluster Anions
文献类型：期刊论文
| 作者 | Wu, Xia; Qin, Zheng-bo; Xie, Hua; Wu, Xiao-hu; Cong, Ran; Tang, Zi-chao |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2010-08-01 |
| 卷号 | 23期号:4页码:373-380 |
| 关键词 | Laser vaporization source Photodetachment Cluster |
| 产权排序 | 1;1 |
| 通讯作者 | 唐紫超 |
| 英文摘要 | we describe a collinear velocity-map photoelectron imaging spectrometer, which combines a wiley-mclaren time-of-flight mass analyzer with a dual-valve laser vaporization source for investigating size-selected cluster and reaction intermediate anions. to generate the reaction anions conveniently, two pulsed valves and a reaction channel are employed instead of premixing carrier gas. the collinear photoelectron imaging spectrometer adopts modified velocity-map electrostatic lens, and provides kinetic energy resolution better than 3%. the performance of the instrument is demonstrated on the photodetachment of si(4)(-) at 532 and 355 nm, and si(3)c(-) at 532 nm, respectively. in both cases, photoelectron spectra and anisotropy parameters are obtained from the images. for si(4)(-) the spectra show two well-resolved vibrational progressions which correspond to the ground state and the first excited state of the neutral si(4) with peak spacing of 330 and 312 cm(-1), respectively. preliminary results suggest that the apparatus is a powerful tool for characterizing the electronic structure and photodetachment dynamics of cluster anions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | flight mass-spectrometer ; electrospray-ionization ; electronic-structures ; negative-ions ; spectroscopy ; photodetachment ; dynamics ; photodissociation ; complexes ; resolution |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000281763700001 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103269]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Xia,Qin, Zheng-bo,Xie, Hua,et al. Collinear Velocity-map Photoelectron Imaging Spectrometer for Cluster Anions[J]. chinese journal of chemical physics,2010,23(4):373-380. |
| APA | Wu, Xia,Qin, Zheng-bo,Xie, Hua,Wu, Xiao-hu,Cong, Ran,&Tang, Zi-chao.(2010).Collinear Velocity-map Photoelectron Imaging Spectrometer for Cluster Anions.chinese journal of chemical physics,23(4),373-380. |
| MLA | Wu, Xia,et al."Collinear Velocity-map Photoelectron Imaging Spectrometer for Cluster Anions".chinese journal of chemical physics 23.4(2010):373-380. |
入库方式： OAI收割
来源：大连化学物理研究所
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