Highly enantioselective michael addition of malononitrile to alpha,beta-unsaturated ketones
文献类型：期刊论文
| 作者 | Li, Xuefeng1,2,4; Cun, Lingfeng1,2; Lian, Chunxia1,2; Zhong, Ling1,2; Chen, Yingchun3; Liao, Jian1,2; Zhu, Jin1,2; Deng, Jingen1,2 |
| 刊名 | Organic & biomolecular chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 6期号:2页码:349-353 |
| ISSN号 | 1477-0520 |
| DOI | 10.1039/b713129a |
| 通讯作者 | Deng, jingen(jgdeng@cioc.ac.cn) |
| 英文摘要 | The highly enantioselective michael addition of malononitrile to acyclic and cyclic alpha,beta-unsaturated ketones has been developed. the michael reaction catalyzed by a primary amine derived from quinidine proceeded smoothly and provided the desired adducts with excellent enantioselectivities (83-97% ee). |
| WOS关键词 | ASYMMETRIC CONJUGATE ADDITION ; CINCHONA ALKALOID DERIVATIVES ; FRIEDEL-CRAFTS ALKYLATION ; AZA-HENRY REACTION ; BIFUNCTIONAL ORGANOCATALYST ; 1,3-DICARBONYL COMPOUNDS ; TRANSFER HYDROGENATION ; PRIMARY AMINES ; ENONES ; CATALYSIS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000252106700017 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2391609 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Deng, Jingen |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmet Synth & Chirotechnol Sichuan Prov, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 3.Sichuan Univ, W China Sch Pharm, Chengdu 610041, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xuefeng,Cun, Lingfeng,Lian, Chunxia,et al. Highly enantioselective michael addition of malononitrile to alpha,beta-unsaturated ketones[J]. Organic & biomolecular chemistry,2008,6(2):349-353. |
| APA | Li, Xuefeng.,Cun, Lingfeng.,Lian, Chunxia.,Zhong, Ling.,Chen, Yingchun.,...&Deng, Jingen.(2008).Highly enantioselective michael addition of malononitrile to alpha,beta-unsaturated ketones.Organic & biomolecular chemistry,6(2),349-353. |
| MLA | Li, Xuefeng,et al."Highly enantioselective michael addition of malononitrile to alpha,beta-unsaturated ketones".Organic & biomolecular chemistry 6.2(2008):349-353. |
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来源：中国科学院大学
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