Preparation of colorless ionic liquids "on water" for spectroscopy
文献类型：期刊论文
| 作者 | Shen, Yanfei; Zhang, Yuanjian; Han, Dongxue; Wang, Zhijuan; Kuehner, Daniel; Niu, Li1 |
| 刊名 | Talanta
 |
| 出版日期 | 2009-05-15 |
| 卷号 | 78期号:3页码:805-808 |
| 关键词 | Ionic liquids Colorless On water Green chemistry Spectroscopy |
| ISSN号 | 0039-9140 |
| DOI | 10.1016/j.talanta.2008.12.056 |
| 通讯作者 | Niu, li(lniu@ciac.jl.cn) |
| 英文摘要 | Although colorless ionic liquids (ils) are most desirable, as synthesized they frequently bear color, despite appearing pure by most analytical techniques. it leads to some uncertainties and limits for the fundamental research and applications of ils, such as spectroscopy. using 1-butyl-3-methylimidazolium bromide (bmimbr), 1-butyl-3-methylimidazolium tetrafluoroborate (bmimbf(4)) and 1-hexyl-3-methylimidazolium bromide (hmimbr) as models, we demonstrated that following classic preparing method except that the water was added as solvent, colorless ils could be facilely prepared. neither critical pre-treatment of starting materials and pre-cautions during the reaction nor time-consuming and costly post-decolor-purification was needed, the effects of "on water" reaction conditions on preparing colorless il and the reason why using water as solvent could produce colorless ils were also preliminary investigated. it was found that the reactant solubility played an important role in the preparation of colorless ils. not only as a method to evaluate the quality of as-synthesized ils. but also as a spectroscopic analytical applications, uv-vis spectra showed that the ils by this "on water" method was spectral pure and sufficient for future fundamental spectroscopic research and applications. (c) 2009 elsevier b.v. all rights reserved. |
| WOS关键词 | IMIDAZOLIUM ; CHEMISTRY ; CELLS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000264976600027 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2395259 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Niu, Li |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Electroanalyt Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Yanfei,Zhang, Yuanjian,Han, Dongxue,et al. Preparation of colorless ionic liquids "on water" for spectroscopy[J]. Talanta,2009,78(3):805-808. |
| APA | Shen, Yanfei,Zhang, Yuanjian,Han, Dongxue,Wang, Zhijuan,Kuehner, Daniel,&Niu, Li.(2009).Preparation of colorless ionic liquids "on water" for spectroscopy.Talanta,78(3),805-808. |
| MLA | Shen, Yanfei,et al."Preparation of colorless ionic liquids "on water" for spectroscopy".Talanta 78.3(2009):805-808. |
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来源：中国科学院大学
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