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Fabrication of fe(cn)(6)(3-) functionalized pdda/cdte layer-by-layer film with good electron transfer ability

文献类型:期刊论文

作者Luan, Qingfen1; Li, Jun2; Yao, Xin1
刊名Electroanalysis
出版日期2009-08-01
卷号21期号:16页码:1799-1804
关键词Layer-by-layer Quantum dots Fe(cn)(6)(3-) Electron transfer Metal ion detection
ISSN号1040-0397
DOI10.1002/elan.200904603
通讯作者Yao, xin(yaox@gucas.ac.cn)
英文摘要(pdda/cdte)(n) layer-by-layer (lbl) film immobilized with fe(cn)(6)(3-) was fabricated on the gold electrode. electrochemical impedance spectroscopy (eis) and cyclic voltammetry (cv) were used to investigate the electrochemical properties of this film. the peak current of the immobilized fe(cn)(6)(3-) increased as the number of the bilayers increased and was proportional to the scan rate. compared with pure (pdda/cdte)(n) and (pdda/pss)(n) lbl film, fe(cn)(6)(3-) immobilized (pdda/cdte)(n) lbl film had good electron transfer ability. the immobility of fe(cn)(6)(3-) into the film was attributed to its interaction with cd2+ on the surface of cdte qds. fe(cn)(6)(3-) also can interact with other metal ions, which would make fe(cn)(6)(3-) release from the film. the concentrations of metal ions will affect the cv response of fe(cn)(6)(3-) immobilized lbl film. it has provided a novel prototype of device or sensor for quantitative detection of metal ions.
WOS关键词SEMICONDUCTOR QUANTUM DOTS ; CDTE NANOCRYSTALS ; NANOPARTICLE ARRAYS ; THIN-FILMS ; GOLD ; CDS ; SURFACTANT ; ASSEMBLIES ; BIOSENSOR ; POLYMER
WOS研究方向Chemistry ; Electrochemistry
WOS类目Chemistry, Analytical ; Electrochemistry
语种英语
WOS记录号WOS:000269425100005
出版者WILEY-BLACKWELL
URI标识http://www.irgrid.ac.cn/handle/1471x/2395765
专题中国科学院大学
通讯作者Yao, Xin
作者单位1.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
2.Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
推荐引用方式
GB/T 7714
Luan, Qingfen,Li, Jun,Yao, Xin. Fabrication of fe(cn)(6)(3-) functionalized pdda/cdte layer-by-layer film with good electron transfer ability[J]. Electroanalysis,2009,21(16):1799-1804.
APA Luan, Qingfen,Li, Jun,&Yao, Xin.(2009).Fabrication of fe(cn)(6)(3-) functionalized pdda/cdte layer-by-layer film with good electron transfer ability.Electroanalysis,21(16),1799-1804.
MLA Luan, Qingfen,et al."Fabrication of fe(cn)(6)(3-) functionalized pdda/cdte layer-by-layer film with good electron transfer ability".Electroanalysis 21.16(2009):1799-1804.

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来源:中国科学院大学

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