Tetra-(tetraalkylammonium)octamolybdate catalysts for selective oxidation of sulfides to sulfoxides with hydrogen peroxide
文献类型:期刊论文
作者 | Yang, Chuanbo1,2,4; Jin, Qingping3; Zhang, Hua1,2; Liao, Jian1,2; Zhu, Jin1,2; Yu, Bin3; Deng, Jingen1,2 |
刊名 | Green chemistry
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出版日期 | 2009 |
卷号 | 11期号:9页码:1401-1405 |
ISSN号 | 1463-9262 |
DOI | 10.1039/b912521n |
通讯作者 | Yang, chuanbo() |
英文摘要 | Tetra-(tetraalkylammonium)octamolybdate catalysts are successfully applied in the selective oxidation of various sulfides to sulfoxides with 30% aqueous hydrogen peroxide as oxidant under mild reaction conditions in 94-100% yield and 95-100% selectivity. the octamolybdate catalysts show high catalytic activity in a high ratio of substrate to catalyst (up to 10000:1) and are recyclable, with actively functional groups, including hydroxyl group and c=c bonds, tolerated in the oxidation. |
WOS关键词 | METHYL PHENYL SULFIDE ; L-CYSTEINE SULFOXIDE ; OXOPEROXO MOLYBDENUM(VI) ; HETEROGENEOUS CATALYST ; SOLVENT-FREE ; H2O2 ; SULFONES ; OLEFINS ; TUNGSTEN(VI) ; PHARMACOLOGY |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000269493700018 |
出版者 | ROYAL SOC CHEMISTRY |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2398650 |
专题 | 中国科学院大学 |
通讯作者 | Yang, Chuanbo |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Sichuan Prov, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol, Chengdu 610041, Sichuan Prov, Peoples R China 3.Zhejiang Jinhua CONBA Biopharm Co Ltd, Jinhua 321016, Zhejiang, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Chuanbo,Jin, Qingping,Zhang, Hua,et al. Tetra-(tetraalkylammonium)octamolybdate catalysts for selective oxidation of sulfides to sulfoxides with hydrogen peroxide[J]. Green chemistry,2009,11(9):1401-1405. |
APA | Yang, Chuanbo.,Jin, Qingping.,Zhang, Hua.,Liao, Jian.,Zhu, Jin.,...&Deng, Jingen.(2009).Tetra-(tetraalkylammonium)octamolybdate catalysts for selective oxidation of sulfides to sulfoxides with hydrogen peroxide.Green chemistry,11(9),1401-1405. |
MLA | Yang, Chuanbo,et al."Tetra-(tetraalkylammonium)octamolybdate catalysts for selective oxidation of sulfides to sulfoxides with hydrogen peroxide".Green chemistry 11.9(2009):1401-1405. |
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来源:中国科学院大学
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