In situ quaterizable oligo-organophosphazene electrolyte with modified nanocomposite sio2 for all-solid-state dye-sensitized solar cell
文献类型：期刊论文
| 作者 | Xiang, Wanchun1,2; Zhou, Yanfang1,2; Yin, Xiong1,2; Zhou, Xiaowen1; Fang, Shibi1; Lin, Yuan1 |
| 刊名 | Electrochimica acta
 |
| 出版日期 | 2009-07-01 |
| 卷号 | 54期号:17页码:4186-4191 |
| 关键词 | In situ quaterization reaction Latent cross-linked precursor All-solid-state electrolyte Nanocomposite Dye-sensitized solar cell |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2009.02.063 |
| 通讯作者 | Fang, shibi(fangsb@iccas.ac.cn) |
| 英文摘要 | Two latent chemical cross-linked precursors: (1) oligo-organophosphazene with propionitrile and iodo(ethylene oxide-co-propylene oxide) and (2) oligo-organosiloxane grafting oligo-ethylene oxide and propylene oxide dimethylamine are synthesized to form all-solid-state polymer electrolyte for dye-sensitized solar cells employing in situ quaterization reaction. this novel electrolyte shows about 6.79 x 10(-7) cm(2) s(-1) of the apparent diffusion coefficient of triiodide. the disintegrating temperature of 181 degrees c demonstrates good thermal stability of the solid-state electrolyte. proper amount of 7 nm sio2 modified with 3-triethoxysilylpropyl oligo(oxyethylene-co-oxypropylene) monomethyl urethane is added to the electrolyte and the photocurrent conversion efficiency reaches 2.66% compared with that of 1.81% with no additive. (c) 2009 elsevier ltd. all rights reserved. |
| WOS关键词 | POLYMER ELECTROLYTES ; GEL ELECTROLYTES ; IODINE ; POLYPHOSPHAZENES ; PERFORMANCE |
| WOS研究方向 | Electrochemistry |
| WOS类目 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000266416800007 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2402402 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Fang, Shibi |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Wanchun,Zhou, Yanfang,Yin, Xiong,et al. In situ quaterizable oligo-organophosphazene electrolyte with modified nanocomposite sio2 for all-solid-state dye-sensitized solar cell[J]. Electrochimica acta,2009,54(17):4186-4191. |
| APA | Xiang, Wanchun,Zhou, Yanfang,Yin, Xiong,Zhou, Xiaowen,Fang, Shibi,&Lin, Yuan.(2009).In situ quaterizable oligo-organophosphazene electrolyte with modified nanocomposite sio2 for all-solid-state dye-sensitized solar cell.Electrochimica acta,54(17),4186-4191. |
| MLA | Xiang, Wanchun,et al."In situ quaterizable oligo-organophosphazene electrolyte with modified nanocomposite sio2 for all-solid-state dye-sensitized solar cell".Electrochimica acta 54.17(2009):4186-4191. |
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来源：中国科学院大学
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