Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes
文献类型：期刊论文
| 作者 | Wang, Peng1,2,3; Chen, Junmin1,2,3,4; Cun, Linfeng1,2; Deng, Jingen1,2,3; Zhu, Jin1,2,3; Liao, Jian1,2,3 |
| 刊名 | Organic & biomolecular chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 7期号:18页码:3741-3747 |
| ISSN号 | 1477-0520 |
| DOI | 10.1039/b909850j |
| 通讯作者 | Liao, jian(jliao10@cioc.ac.cn) |
| 英文摘要 | A series of enantiomerically pure mono- and bis-aryl tert-butyl sulfoxides were synthesised to promote the enantioselective allylation of aldehydes with allyltrichlorosilane. moderate to good yields and modest to high enantioselectivities were achieved. the absence of nonlinear effect, spacer effect, promoter loading and concentration effect indicate that only one molecule of aryl tert-butyl sulfoxide is involved in the stereodetermining step. |
| WOS关键词 | CATALYTIC ASYMMETRIC ALLYLATION ; PHOSPHORUS-BASED AMIDES ; CHIRAL LEWIS-BASES ; PYRIDINE N-OXIDES ; ALLYLIC TRICHLOROSILANES ; BUTANESULFINYL IMINES ; HOMOALLYLIC ALCOHOLS ; AROMATIC-ALDEHYDES ; BIS(SULFINYL)IMIDOAMIDINE LIGANDS ; ORGANOCATALYSTS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000269327500017 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2404078 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liao, Jian |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Peng,Chen, Junmin,Cun, Linfeng,et al. Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes[J]. Organic & biomolecular chemistry,2009,7(18):3741-3747. |
| APA | Wang, Peng,Chen, Junmin,Cun, Linfeng,Deng, Jingen,Zhu, Jin,&Liao, Jian.(2009).Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes.Organic & biomolecular chemistry,7(18),3741-3747. |
| MLA | Wang, Peng,et al."Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes".Organic & biomolecular chemistry 7.18(2009):3741-3747. |
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来源：中国科学院大学
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