Chemoselective and enantioselective transfer hydrogenation of beta,beta-disubstituted nitroalkenes catalyzed by a water-insoluble chiral diamine-rhodium complex in water
文献类型：期刊论文
| 作者 | Tang, Yuanfu1,2,3; Xiang, Jing1,2,3; Cun, Linfeng1,2; Wang, Yuqin1,2; Zhu, Jin1,2; Liao, Jian1,2; Deng, Jingen1,2 |
| 刊名 | Tetrahedron-asymmetry
 |
| 出版日期 | 2010-08-04 |
| 卷号 | 21期号:15页码:1900-1905 |
| ISSN号 | 0957-4166 |
| DOI | 10.1016/j.tetasy.2010.05.046 |
| 通讯作者 | Deng, jingen(jgdeng@cioc.ac.cn) |
| 英文摘要 | Asymmetric transfer hydrogenation of beta,beta-disubstituted nitroalkenes catalyzed by a chiral diamine-rhodium complex in combination with hco(2)na-hco(2)h as a hydrogen source in water was successfully realized with high reactivity, excellent chemoselectivity and good enantioselectivity. the metal precursor and ph value of the aqueous solution have a large influence on the reactivity and chemoselectivity. the substituents on the benzene rings and the sulfonyl groups of tsdpen have significant effects on the enantioselectivity. this catalytic asymmetric transformation is one of the most practical pathways to obtain optically active nitroalkanes. (c) 2010 elsevier ltd. all rights reserved, |
| WOS关键词 | ASYMMETRIC TRANSFER HYDROGENATION ; FERMENTING BAKERS-YEAST ; AMIDO COMPLEXES ; CONJUGATE REDUCTION ; RUTHENIUM COMPLEXES ; AROMATIC KETONES ; AQUEOUS-MEDIA ; FORMIC-ACID ; IMINES ; LIGAND |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000281626300015 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2405842 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Deng, Jingen |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Yuanfu,Xiang, Jing,Cun, Linfeng,et al. Chemoselective and enantioselective transfer hydrogenation of beta,beta-disubstituted nitroalkenes catalyzed by a water-insoluble chiral diamine-rhodium complex in water[J]. Tetrahedron-asymmetry,2010,21(15):1900-1905. |
| APA | Tang, Yuanfu.,Xiang, Jing.,Cun, Linfeng.,Wang, Yuqin.,Zhu, Jin.,...&Deng, Jingen.(2010).Chemoselective and enantioselective transfer hydrogenation of beta,beta-disubstituted nitroalkenes catalyzed by a water-insoluble chiral diamine-rhodium complex in water.Tetrahedron-asymmetry,21(15),1900-1905. |
| MLA | Tang, Yuanfu,et al."Chemoselective and enantioselective transfer hydrogenation of beta,beta-disubstituted nitroalkenes catalyzed by a water-insoluble chiral diamine-rhodium complex in water".Tetrahedron-asymmetry 21.15(2010):1900-1905. |
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来源：中国科学院大学
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