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Coordination-induced CO2 fixation into carbonate by metal oxides

文献类型：期刊论文

作者Fan, Hongjun2; Zhao, Zhi1,2; Jiang, Ling2; Kong, Xiangtao2; Yuan, Qinqin2,3; Xie, Hua2; Yang, Dong2,3; Zhao, Jijun1
刊名PHYSICAL CHEMISTRY CHEMICAL PHYSICS
出版日期2018-08-07
卷号20期号:29页码:19314-19320
ISSN号1463-9076
DOI10.1039/c8cp02085j
通讯作者Fan, Hongjun(fanhj@dicp.ac.cn) ; Jiang, Ling(ljiang@dicp.ac.cn)
英文摘要Here, we have investigated how coordination induces CO2 fixation into a carbonate using a cationic yttrium oxide model catalyst. The infrared spectra show that the first three CO2 molecules are weakly bound to the metal. Subsequent coordination of CO2 ligands leads to the formation of a carbonate complex and results in a core ion transition. The conversion of Y = O and CO2 to carbonate is achieved by the donation of electrons from the ligands to the metal. Systematic analyses of the effects of different ligands and metals on the coordination-induced CO2 fixation demonstrate that the present system serves as an efficient and rational model for adjusting CO2 fixation and CO2 emission.
WOS关键词DRIVEN REDUCTIVE ACTIVATION ; INFRARED-SPECTROSCOPY ; SURFACE-CHEMISTRY ; ANIONIC COMPLEXES ; NEGATIVE CHARGE ; DIOXIDE ; CLUSTERS ; ION ; SOLVATION ; SPECTRA
资助项目National Natural Science Foundation of China[21327901] ; National Natural Science Foundation of China[21503222] ; National Natural Science Foundation of China[21673231] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[11574040] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17000000]
WOS研究方向Chemistry ; Physics
语种英语
WOS记录号WOS:000448132600003
出版者ROYAL SOC CHEMISTRY
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166806]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Fan, Hongjun; Jiang, Ling
作者单位1.Dalian Univ Technol, Key Lab Mat Modificat Laser Ion & Electron Beams, Minist Educ, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Fan, Hongjun,Zhao, Zhi,Jiang, Ling,et al. Coordination-induced CO2 fixation into carbonate by metal oxides[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(29):19314-19320.
APA Fan, Hongjun.,Zhao, Zhi.,Jiang, Ling.,Kong, Xiangtao.,Yuan, Qinqin.,...&Zhao, Jijun.(2018).Coordination-induced CO2 fixation into carbonate by metal oxides.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(29),19314-19320.
MLA Fan, Hongjun,et al."Coordination-induced CO2 fixation into carbonate by metal oxides".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.29(2018):19314-19320.

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来源：大连化学物理研究所

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