Cp*Co(III)-catalyzed amidation of olefinic and aryl C-H bonds: highly selective synthesis of enamides and pyrimidones
文献类型：期刊论文
| 作者 | Liu, Yuan1; Xie, Fang2; Jia, Ai-Qun1; Li, Xingwei2 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2018-04-25 |
| 卷号 | 54期号:34页码:4345-4348 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c8cc01447g |
| 文献子类 | Article |
| 英文摘要 | A highly efficient and selective synthesis of enamides via C-H amidation of N-methoxy acrylamides with dioxazolones is realized under [Cp*Co-III] catalysis. The resulting enamide can further selectively cyclize to form pyrimidones, which can also act as a directing group for a second C-H amidation. All these three classes of products were selectively delivered under controlled conditions. |
| WOS关键词 | EFFICIENT SYNTHESIS ; ACTIVATION ; INHIBITORS ; ALKYNES ; DIOXAZOLONES ; QUINAZOLINES ; HETEROCYCLES ; COBALT(III) ; DERIVATIVES ; CYCLIZATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000430935200028 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167176]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Jia, Ai-Qun; Li, Xingwei |
| 作者单位 | 1.Hainan Univ, Dept Pharm, State Key Lab Marine Resource Utilizat South Chin, Key Lab Trop Biol Resources,Minist Educ, Haikou 570228, Hainan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yuan,Xie, Fang,Jia, Ai-Qun,et al. Cp*Co(III)-catalyzed amidation of olefinic and aryl C-H bonds: highly selective synthesis of enamides and pyrimidones[J]. CHEMICAL COMMUNICATIONS,2018,54(34):4345-4348. |
| APA | Liu, Yuan,Xie, Fang,Jia, Ai-Qun,&Li, Xingwei.(2018).Cp*Co(III)-catalyzed amidation of olefinic and aryl C-H bonds: highly selective synthesis of enamides and pyrimidones.CHEMICAL COMMUNICATIONS,54(34),4345-4348. |
| MLA | Liu, Yuan,et al."Cp*Co(III)-catalyzed amidation of olefinic and aryl C-H bonds: highly selective synthesis of enamides and pyrimidones".CHEMICAL COMMUNICATIONS 54.34(2018):4345-4348. |
入库方式： OAI收割
来源：大连化学物理研究所
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