"Three-in-One:" A New 3D Hybrid Structure of Li3V2(PO4)(3) @ Biomorphic Carbon for High-Rate and Low-Temperature Lithium Ion Batteries
文献类型：期刊论文
| 作者 | Cheng, Yi1,2; Feng, Kai2,3; Wang, Huaiqing1,2; Zhang, Hongzhang2,3; Li, Xianfeng2,3; Zhang, Huamin2,3 |
| 刊名 | ADVANCED MATERIALS INTERFACES
 |
| 出版日期 | 2017-11-23 |
| 卷号 | 4期号:22 |
| 关键词 | 3d Hybrid Structures Biomorphic Carbon Lithium Ion Batteries Lithium Vanadium Phosphate |
| ISSN号 | 2196-7350 |
| DOI | 10.1002/admi.201700686 |
| 文献子类 | Article |
| 英文摘要 | Li3V2(PO4)(3) with high specific capacity and high operating potential has been considered as a promising cathode for the next generation lithium ion batteries (LIBs). But the low electronic conductivity restricts its practical applications. Here, a rational design of 3D hybrid structures of Li3V2(PO4)(3) @ biomorphic carbon is presented. The 3D hybrid structures built from 0D, 1D, and 2D composites are carbonized from biomorphic carbon, namely, three-in-one. The synergistic effects of the carbon with different dimensions provide high electronic conductivity and good structural stability. In addition, abundant porous channels in the structure accelerate transfer of the Li+. This unique cathode material reaches the capacity retention up to 96% (relative to 1 C) when the rate increased to 50 C. When combines with Li4Ti5O12 to form a full battery, it delivers a capacity of 174 mAh g(-1) at room temperature and retains 150 mAh g(-1) when the temperature decreases to -40 degrees C. The excellent properties are attributed to the high electronic conductivity, fast ion transport channels, large electrode-electrolyte contact area, and robust structure stability of the 3D hybrid architecture. This work provides a new strategy for constructing 3D framework electrode materials for LIBs. |
| WOS关键词 | HIGH-RATE CAPABILITY ; CATHODE MATERIALS ; LONG-LIFE ; ELECTROCHEMICAL PERFORMANCE ; RECHARGEABLE BATTERIES ; NANOCOMPOSITE CATHODE ; SULFUR BATTERIES ; HIGH-CAPACITY ; STORAGE ; COMPOSITE |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000416253100009 |
| 出版者 | WILEY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168386]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Feng, Kai; Zhang, Huamin |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Yi,Feng, Kai,Wang, Huaiqing,et al. "Three-in-One:" A New 3D Hybrid Structure of Li3V2(PO4)(3) @ Biomorphic Carbon for High-Rate and Low-Temperature Lithium Ion Batteries[J]. ADVANCED MATERIALS INTERFACES,2017,4(22). |
| APA | Cheng, Yi,Feng, Kai,Wang, Huaiqing,Zhang, Hongzhang,Li, Xianfeng,&Zhang, Huamin.(2017)."Three-in-One:" A New 3D Hybrid Structure of Li3V2(PO4)(3) @ Biomorphic Carbon for High-Rate and Low-Temperature Lithium Ion Batteries.ADVANCED MATERIALS INTERFACES,4(22). |
| MLA | Cheng, Yi,et al.""Three-in-One:" A New 3D Hybrid Structure of Li3V2(PO4)(3) @ Biomorphic Carbon for High-Rate and Low-Temperature Lithium Ion Batteries".ADVANCED MATERIALS INTERFACES 4.22(2017). |
入库方式： OAI收割
来源：大连化学物理研究所
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