Regio- and Diastereoselective Access to Fused Isoxazolidines via Ru(II)-Catalyzed C-H Activation of Nitrones and Coupling with Perfluoroalkylolefins
文献类型：期刊论文
| 作者 | Li, Yunyun1,2; Xie, Fang1; Liu, Yuan1; Yang, Xifa1,2; Li, Xingwei1 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2018-01-19 |
| 卷号 | 20期号:2页码:437-440 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.7b03775 |
| 文献子类 | Article |
| 英文摘要 | The synthsis of fluorinated isoxazolidines in bicyclic settings has been realized via Ru(II)-catalyzed C-H activation of aryl nitrones with perfluoroalkyl-substituted olefins as the coupling partner. The reaction proceeded via initial chelation-assisted C(aryl)-H allylation followed by regio- and diastereoselective intramolecular dipolar addition between the nitrone directing group and the olefin unit. |
| WOS关键词 | 1,3-DIPOLAR CYCLOADDITION REACTIONS ; ENANTIOSELECTIVE FLUORINATION ; AZOMETHINE YLIDES ; ORGANIC-SYNTHESIS ; ROOM-TEMPERATURE ; DIRECTING GROUPS ; ZETEKITOXIN-AB ; FUNCTIONALIZATION ; FLUOROALKENYLATION ; PALLADIUM |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000423252400031 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168610]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yunyun,Xie, Fang,Liu, Yuan,et al. Regio- and Diastereoselective Access to Fused Isoxazolidines via Ru(II)-Catalyzed C-H Activation of Nitrones and Coupling with Perfluoroalkylolefins[J]. ORGANIC LETTERS,2018,20(2):437-440. |
| APA | Li, Yunyun,Xie, Fang,Liu, Yuan,Yang, Xifa,&Li, Xingwei.(2018).Regio- and Diastereoselective Access to Fused Isoxazolidines via Ru(II)-Catalyzed C-H Activation of Nitrones and Coupling with Perfluoroalkylolefins.ORGANIC LETTERS,20(2),437-440. |
| MLA | Li, Yunyun,et al."Regio- and Diastereoselective Access to Fused Isoxazolidines via Ru(II)-Catalyzed C-H Activation of Nitrones and Coupling with Perfluoroalkylolefins".ORGANIC LETTERS 20.2(2018):437-440. |
入库方式： OAI收割
来源：大连化学物理研究所
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