Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6)
文献类型：期刊论文
| 作者 | Fan, Hongjun1; Xie, Hua1; Zou, Jinghan1,2; Yuan, Qinqin1,2; Zhang, Jumei1,2; Jiang, Ling1 |
| 刊名 | TOPICS IN CATALYSIS
 |
| 出版日期 | 2018-03-01 |
| 卷号 | 61期号:1-2页码:71-80 |
| 关键词 | Photoelectron Spectroscopy Co Activation Heteronuclear Metal Carbonyl Quantum Chemical Calculation |
| ISSN号 | 1022-5528 |
| DOI | 10.1007/s11244-017-0875-0 |
| 文献子类 | Article |
| 英文摘要 | The chemical bonding and electronic structure of heteronuclear metal-nickel carbonyls MNi(CO)(n)(-) (M = Sc, Y; n = 2-6) have been investigated by mass-selected photoelectron velocity map imaging spectroscopy and quantum chemical calculations. Two CO bonding modes (side-on-bonded and terminal carbonyls) are involved in the n = 2 cluster. The building block composed of three kinds of different CO modes (side-on-bonded, bridging, and terminal carbonyls) is favored at n = 3, the structure of which persists up to n = 6. The additional CO ligands are preferentially coordinated in the terminal mode to the Sc atom and then to the Ni atom in the larger clusters. The present findings would promote the understanding of CO molecule activation and chemisorbed CO molecules on metal surfaces. |
| WOS关键词 | INFRARED PHOTODISSOCIATION SPECTROSCOPY ; DENSITY-FUNCTIONAL CALCULATIONS ; GAS-PHASE ; CLUSTER CATIONS ; COPPER CARBONYLS ; SOLID ARGON ; SPECTRA ; ATOMS ; MONOXIDE ; ANIONS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000428065700009 |
| 出版者 | SPRINGER/PLENUM PUBLISHERS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169068]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Jiang, Ling |
| 作者单位 | 1.Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy & Mat iChEM, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Hongjun,Xie, Hua,Zou, Jinghan,et al. Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6)[J]. TOPICS IN CATALYSIS,2018,61(1-2):71-80. |
| APA | Fan, Hongjun,Xie, Hua,Zou, Jinghan,Yuan, Qinqin,Zhang, Jumei,&Jiang, Ling.(2018).Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6).TOPICS IN CATALYSIS,61(1-2),71-80. |
| MLA | Fan, Hongjun,et al."Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-Nickel Carbonyls MNi(CO)(n)(-) (M = Sc, Y; n=2-6)".TOPICS IN CATALYSIS 61.1-2(2018):71-80. |
入库方式： OAI收割
来源：大连化学物理研究所
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