Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction
文献类型：期刊论文
| 作者 | Lian, Tianquan4; Tian, Wenming1,2; Cui, Rongrong1,2; Leng, Jing1,2; Liu, Junxue3; Li, Yajuan1,2; Zhao, Chunyi1,2; Zhang, Jun3; Deng, Weiqiao1,2; Jin, Shengye1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-10-10 |
| 卷号 | 55期号:42页码:13067-13071 |
| 关键词 | Charge Carriers Grain Boundaries Perovskites Photoluminescence Mapping Solar Cells |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201606574 |
| 文献子类 | Article |
| 英文摘要 | Although the power conversion efficiency of perovskite solar cells has improved rapidly, a rational path for further improvement remains unclear. The effect of large morphological heterogeneity of polycrystalline perovskite films on their device performance by photoluminescence (PL) microscopy has now been studied. Contrary to the common belief on the deleterious effect of morphological heterogeneity on carrier lifetimes and diffusivities, in neat CH3NH3PbI3(Cl) polycrystalline perovskite films, the local (intra-grain) carrier diffusivities in different grains are all surprisingly high (1.5 to 3.3 cm(2) s(-1); comparable to bulk single-crystals), and the local carrier lifetimes are long (ca. 200 ns) and surprisingly homogenous among grains, and uniform across grain boundary and interior. However, there is a large heterogeneity of carrier extraction efficiency at the perovskite grain-electrode interface. Improving homogeneity at perovskite grain-electrode contacts is thus a promising direction for improving the performance of perovskite thin-film solar cells. |
| WOS关键词 | THIN-FILMS ; SINGLE-CRYSTALS ; HALIDE PEROVSKITES ; DIFFUSION ; RECOMBINATION ; PHOTOVOLTAICS ; MOBILITIES ; DEPOSITION ; ABSORBER |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000385799200020 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169976]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lian, Tianquan; Jin, Shengye |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 ZhongShan Rd, Dalian 116023, Peoples R China 2.Collaborat Innovat Ctr Chem Energy Mat IChEM, 457 ZhongShan Rd, Dalian 116023, Peoples R China 3.China Univ Petr, Dept Chem, 66 Changjiang West Rd, Qingdao 266580, Peoples R China 4.Emory Univ, Dept Chem, 1515 Dickey Dr, Atlanta, GA 30322 USA |
| 推荐引用方式 GB/T 7714 | Lian, Tianquan,Tian, Wenming,Cui, Rongrong,et al. Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(42):13067-13071. |
| APA | Lian, Tianquan.,Tian, Wenming.,Cui, Rongrong.,Leng, Jing.,Liu, Junxue.,...&Jin, Shengye.(2016).Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(42),13067-13071. |
| MLA | Lian, Tianquan,et al."Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.42(2016):13067-13071. |
入库方式： OAI收割
来源：大连化学物理研究所
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