中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 大连化学物理研究所
  3. 中国科学院大连化学物理研究所
Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters

文献类型：期刊论文

作者Yang, Dong1,2; Su, Ming-zhi1,2; Zheng, Hui-jun1,2; Zhao, Zhi2; Li, Gang2; Kong, Xiang-tao2; Xie, Hua2; Fan, Hong-jun2; Zhang, Wei-qing2; Jiang, Ling2
刊名CHINESE JOURNAL OF CHEMICAL PHYSICS
出版日期2019-04-01
卷号32期号:2页码:223-228
关键词Cationic cobalt Carbon dioxide Structure Infrared photodissociation spectroscopy Quantum chemical calculation
ISSN号1674-0068
DOI10.1063/1674-0068/cjcp1902032
通讯作者Jiang, Ling(ljiang@dicp.ac.cn)
英文摘要The mass-selected infrared photodissociation (IRPD) spectroscopy was utilized to investigate the interactions of cationic cobalt with carbon dioxide molecules. Quantum chemical calculations were performed on the [Co(CO2)(n)](+) clusters to identify the structures of the low-lying isomers and to assign the observed spectral features. All the [Co(CO2)(n)](+) (n=2-6) clusters studied here show resonances near the CO2 asymmetric stretch of free CO2 molecule. Experimental and calculated results indicate that the CO2 molecules are weakly bound to the Co+ cations in an end-on configuration via a charge-quadrupole electrostatic interaction. The present IRPD spectra of [Co(CO2)(n)](+) clusters have been compared to those of Ar-tagged species ([Co(CO2)(n)](+)-Ar), which would provide insights into the tagging effect of rare gas on the weakly-bounded clusters.
WOS关键词DRIVEN REDUCTIVE ACTIVATION ; CARBON-DIOXIDE ; ANIONIC COMPLEXES ; GROWTH DYNAMICS ; GAS ; SPECTRA ; SOLVATION ; LANTHANUM ; CHEMISTRY ; ATOMS
资助项目National Natural Science Foundation of China[21327901] ; National Natural Science Foundation of China[21503222] ; National Natural Science Foundation of China[21673231] ; National Natural Science Foundation of China[21688102] ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation[2018M641718] ; China Postdoctoral Science Foundation[2018M641719]
WOS研究方向Physics
语种英语
WOS记录号WOS:000467700000012
出版者CHINESE PHYSICAL SOC
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation
源URL[http://cas-ir.dicp.ac.cn/handle/321008/171873]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Jiang, Ling
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, State Key Lab Mol React Dynam, Collaborat Innovat Ctr Chem Energy & Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714		 Yang, Dong,Su, Ming-zhi,Zheng, Hui-jun,et al. Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2019,32(2):223-228.
APA Yang, Dong.,Su, Ming-zhi.,Zheng, Hui-jun.,Zhao, Zhi.,Li, Gang.,...&Jiang, Ling.(2019).Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters.CHINESE JOURNAL OF CHEMICAL PHYSICS,32(2),223-228.
MLA Yang, Dong,et al."Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)(n)](+) Clusters".CHINESE JOURNAL OF CHEMICAL PHYSICS 32.2(2019):223-228.

入库方式： OAI收割

来源：大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。