Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts
文献类型：期刊论文
| 作者 | Liu, Jian1,2; Zhu, Yanan1,2; Liu, Chang1,2; Wang, Xiaoshi1,2; Cao, Changyan1,2; Song, Weiguo1,2 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2017-11-09 |
| 卷号 | 9期号:21页码:4053-4057 |
| 关键词 | Alkynes Alloys Hydrogenation Selectivity Supported Catalysts |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.201700800 |
| 英文摘要 | A series of active-carbon-supported PdPb and PdCu bimetal catalysts were prepared for the selective semihydrogenation of alkynes in the liquid phase. The Pd0.33Pb0.67/C catalyst showed the best performance for various alkynes under mild reaction conditions (room temperature and ambient H-2 pressure) and achieved 100% conversion with 98% selectivity to alkenes. In particular, over-hydrogenation was avoided at complete alkyne conversion. |
| 语种 | 英语 |
| WOS记录号 | WOS:000417441400007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45341]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cao, Changyan; Song, Weiguo |
| 作者单位 | 1.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jian,Zhu, Yanan,Liu, Chang,et al. Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts[J]. CHEMCATCHEM,2017,9(21):4053-4057. |
| APA | Liu, Jian,Zhu, Yanan,Liu, Chang,Wang, Xiaoshi,Cao, Changyan,&Song, Weiguo.(2017).Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts.CHEMCATCHEM,9(21),4053-4057. |
| MLA | Liu, Jian,et al."Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts".CHEMCATCHEM 9.21(2017):4053-4057. |
入库方式： OAI收割
来源：化学研究所
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