Improved synthesis of 5,5-diamino BINAP and application to asymmetric hydrogenation
文献类型：期刊论文
| 作者 | Huang, YY; Deng, GJ; Wang, XY; He, YM; Fan, QH |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2004-09-01 |
| 卷号 | 22期号:9页码:891-893 |
| 关键词 | Binap Asymmetric Hydrogenation Nitration |
| ISSN号 | 1001-604X |
| 英文摘要 | 5,5-Diamino BINAP has been synthesized via three steps using BINAPO as starting material with high reaction yield. Present method needed only a stoichiometric quantity of nitric acid in the step of nitration of BINAPO, giving almost quantitative reaction yield. Based on 5,5-diamino BINAP, other three new BINAP derivatives have been synthesized. These modified BINAP ligands; showed better catalytic properties as compared to BINAP itself in the asymmetric hydrogenation of 2-(6'-methoxyl-2'-naphthyl)acrylic acid. |
| 语种 | 英语 |
| WOS记录号 | WOS:000223842000002 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55395]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, QH |
| 作者单位 | 1.Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, YY,Deng, GJ,Wang, XY,et al. Improved synthesis of 5,5-diamino BINAP and application to asymmetric hydrogenation[J]. CHINESE JOURNAL OF CHEMISTRY,2004,22(9):891-893. |
| APA | Huang, YY,Deng, GJ,Wang, XY,He, YM,&Fan, QH.(2004).Improved synthesis of 5,5-diamino BINAP and application to asymmetric hydrogenation.CHINESE JOURNAL OF CHEMISTRY,22(9),891-893. |
| MLA | Huang, YY,et al."Improved synthesis of 5,5-diamino BINAP and application to asymmetric hydrogenation".CHINESE JOURNAL OF CHEMISTRY 22.9(2004):891-893. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。