Influence of 1-butanethiol and metal ions on hydrogenation of trans,trans-2,4-hexadienal at platinum nanocatalysts
文献类型：期刊论文
| 作者 | Du, YK; Xu, JZ; Yang, P; Hua, NP; Jiang, L |
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2005-05-05 |
| 卷号 | 257-58页码:75-78 |
| 关键词 | Platinum Nanocatalyst Selectivity Trans.trans-2 4-hexadienal |
| ISSN号 | 0927-7757 |
| DOI | 10.1016/j.colsurfa.2004.10.043 |
| 英文摘要 | The catalytic behavior of platinum nanoparticles modified by iron (III) ions and 1-butanethiol was evaluated by determining the selectivity of hydrogenation of trans,trans-2.4-hexadienal, where the hydrogenation products were monitored by UV-vis spectroscopy and gas chromatograph. For the pure platinum nanoparticles, the selectivity to trans,trans-2,4-hexadienal is less than 5%; while for platinum nanoparticles modified by iron (III) ions and 1-butanethiol, the selectivity increased to 78% with a conversion of 86.5%. The enhancement in the selectivity of the reaction can be attributed to the synergic effects of iron (III) and 1-butanethiol. (c) 2004 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000228321500016 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56863]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Du, YK |
| 作者单位 | 1.Suzhou Univ, Dept Chem, Suzhou 215006, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Colloid & Surfaces, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, YK,Xu, JZ,Yang, P,et al. Influence of 1-butanethiol and metal ions on hydrogenation of trans,trans-2,4-hexadienal at platinum nanocatalysts[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2005,257-58:75-78. |
| APA | Du, YK,Xu, JZ,Yang, P,Hua, NP,&Jiang, L.(2005).Influence of 1-butanethiol and metal ions on hydrogenation of trans,trans-2,4-hexadienal at platinum nanocatalysts.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,257-58,75-78. |
| MLA | Du, YK,et al."Influence of 1-butanethiol and metal ions on hydrogenation of trans,trans-2,4-hexadienal at platinum nanocatalysts".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 257-58(2005):75-78. |
入库方式： OAI收割
来源：化学研究所
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