Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent
文献类型：期刊论文
| 作者 | Li, Wei1,2; Jiang, Wei1,2 |
| 刊名 | MACROMOLECULAR THEORY AND SIMULATIONS
 |
| 出版日期 | 2009-10-27 |
| 卷号 | 18期号:7-8页码:434-440 |
| 关键词 | Amphiphilic Diblock Copolymer Selectivity Self-assembly Self-consistent Field Theory Solvent Molecular Size |
| ISSN号 | 1022-1344 |
| DOI | 10.1002/mats.200900033 |
| 英文摘要 | Real-space self-consistent field theory (SCFT) is employed to study the effect of solvent molecular size on the self-assembly of amphiphilic diblock copolymer in selective solvent. The phase diagrams in wide ranges of interaction parameters and solvent molecular size were obtained in present study. The results indicate that the solvent molecular size is a key factor that determines the self-assembly of amphiphilic diblock copolymer. The self-assembled morphology changes from circle-like micelle to line-like micelle, then to loop-like micelle by decreasing the solvent molecular size in a wide range of solvent selectivity. We analyze and discuss this change in terms of the solvent solubility and the entropy contribution. |
| 语种 | 英语 |
| WOS记录号 | WOS:000271482900005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68025]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Wei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Wei,Jiang, Wei. Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent[J]. MACROMOLECULAR THEORY AND SIMULATIONS,2009,18(7-8):434-440. |
| APA | Li, Wei,&Jiang, Wei.(2009).Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent.MACROMOLECULAR THEORY AND SIMULATIONS,18(7-8),434-440. |
| MLA | Li, Wei,et al."Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent".MACROMOLECULAR THEORY AND SIMULATIONS 18.7-8(2009):434-440. |
入库方式： OAI收割
来源：化学研究所
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