Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent
文献类型：期刊论文
| 作者 | Li, Wei1,2; Jiang, Wei1,2 |
| 刊名 | POLYMER BULLETIN
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 64期号:8页码:805-815 |
| 关键词 | Conformational Asymmetry Diblock Copolymer Self-assembly Selectivity Self-consistent Field Theory |
| ISSN号 | 0170-0839 |
| DOI | 10.1007/s00289-010-0265-2 |
| 英文摘要 | Three dimensional real-space self-consistent field theory is employed to study the effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent. The phase diagrams in wide ranges of interaction parameters and conformational asymmetry were obtained in present study. The results indicate that the conformational asymmetry is an important factor that determines the self-assembly of amphiphilic diblock copolymer in solution. The self-assembled morphology changes from sphere to rod, then to vesicle with an increase of the degree of conformational asymmetry. We found that the entropic contribution of the core-forming block is the main reason for this transition. |
| 语种 | 英语 |
| WOS记录号 | WOS:000276440300007 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70417]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Wei |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Wei,Jiang, Wei. Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent[J]. POLYMER BULLETIN,2010,64(8):805-815. |
| APA | Li, Wei,&Jiang, Wei.(2010).Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent.POLYMER BULLETIN,64(8),805-815. |
| MLA | Li, Wei,et al."Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent".POLYMER BULLETIN 64.8(2010):805-815. |
入库方式： OAI收割
来源：化学研究所
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