中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent

文献类型:期刊论文

作者Li, Wei1,2; Jiang, Wei1,2
刊名POLYMER BULLETIN
出版日期2010-05-01
卷号64期号:8页码:805-815
关键词Conformational Asymmetry Diblock Copolymer Self-assembly Selectivity Self-consistent Field Theory
ISSN号0170-0839
DOI10.1007/s00289-010-0265-2
英文摘要Three dimensional real-space self-consistent field theory is employed to study the effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent. The phase diagrams in wide ranges of interaction parameters and conformational asymmetry were obtained in present study. The results indicate that the conformational asymmetry is an important factor that determines the self-assembly of amphiphilic diblock copolymer in solution. The self-assembled morphology changes from sphere to rod, then to vesicle with an increase of the degree of conformational asymmetry. We found that the entropic contribution of the core-forming block is the main reason for this transition.
语种英语
WOS记录号WOS:000276440300007
出版者SPRINGER
源URL[http://ir.iccas.ac.cn/handle/121111/70417]  
专题中国科学院化学研究所
通讯作者Jiang, Wei
作者单位1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
推荐引用方式
GB/T 7714
Li, Wei,Jiang, Wei. Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent[J]. POLYMER BULLETIN,2010,64(8):805-815.
APA Li, Wei,&Jiang, Wei.(2010).Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent.POLYMER BULLETIN,64(8),805-815.
MLA Li, Wei,et al."Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent".POLYMER BULLETIN 64.8(2010):805-815.

入库方式: OAI收割

来源:化学研究所

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