Dendronized poly(Ru-BINAP) complexes: Highly effective and easily recyclable catalysts for asymmetric hydrogenation
文献类型：期刊论文
| 作者 | Deng, GJ; Yi, B; Huang, YY; Tang, WJ; He, YM; Fan, QH |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2004-10-01 |
| 卷号 | 346期号:12页码:1440-1444 |
| 关键词 | Asymmetric Catalysis Dendrimers Hydrogenation Immobilization Soluble Polymer Phosphane Ligands |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.200404162 |
| 英文摘要 | A new kind of dendronized polymeric chiral BINAP ligands has been synthesized and applied to the Ru-catalyzed asymmetric hydrogenation of simple aryl ketones and 2-arylacrylic acids. These dendronized poly(Ru-BINAP) catalysts exhibited high catalytic activity and enantioselectivity, very similar to those obtained with the corresponding parent Ru(BINAP) and the Ru(BINAP)-cored dendrimers. It was found that the pendant dendrons had a major impact on the solubility and the catalytic properties of the polymeric ligands. These polymeric catalysts could be easily recovered from the reaction solution by using solvent precipitation, and the reused catalyst showed no loss of activity or enantioselectivity. |
| 语种 | 英语 |
| WOS记录号 | WOS:000224969200005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81931]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, QH |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Biol Chem Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, GJ,Yi, B,Huang, YY,et al. Dendronized poly(Ru-BINAP) complexes: Highly effective and easily recyclable catalysts for asymmetric hydrogenation[J]. ADVANCED SYNTHESIS & CATALYSIS,2004,346(12):1440-1444. |
| APA | Deng, GJ,Yi, B,Huang, YY,Tang, WJ,He, YM,&Fan, QH.(2004).Dendronized poly(Ru-BINAP) complexes: Highly effective and easily recyclable catalysts for asymmetric hydrogenation.ADVANCED SYNTHESIS & CATALYSIS,346(12),1440-1444. |
| MLA | Deng, GJ,et al."Dendronized poly(Ru-BINAP) complexes: Highly effective and easily recyclable catalysts for asymmetric hydrogenation".ADVANCED SYNTHESIS & CATALYSIS 346.12(2004):1440-1444. |
入库方式： OAI收割
来源：化学研究所
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