Mercury (Hg) is an element of environmental and geological significance. Quantification of different Hg-binding forms is crucial to understand geological Hg provenances and associated geochemical processes during coal formation. In this study, seven coal samples were selected, according to coal rank (i.e., middle volatile bituminous, C-3; low volatile bituminous, C-2; anthracite, C-1), chemical anomalies (high S coal, IBC-105; high Cl coal, C22650) and sampling environment (fresh coal, LH; weathered coal LHW), to determine their Hg-binding forms using well-established sequential extraction procedures coupled with sink-float experiment. In the thermally metamorphosed samples C-1 and C-2, a comparative enrichment of total Hg relative to C-3 is observed. Silicate- and organic-bound Hg are the dominant Hg-binding forms in C-1, suggesting possible Hg sources from magma silicate and secondary Hg enrichment by adsorption. Sulfide- and organic-bound Hg are the most abundant Hg-binding forms in IBC-105, whereas only organic-bound Hg dominates in CC22650. Weathering processes are suggested to transform the abundant sulfide-bound Hg in LH to silicate- and organic-bound Hg in its weathering product LHW.