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Automatic estimation of varying continuum background emission in laser-induced breakdown spectroscopy

文献类型:期刊论文

作者Sun LX(孙兰香); Yu HB(于海斌)
刊名Spectrochimica Acta Part B: Atomic Spectroscopy
出版日期2009
卷号64期号:3页码:278-287
关键词Laser-induced breakdown spectroscopy Background estimation Line overlaps Polynomial function Parameter optimization
ISSN号0584-8547
产权排序1
通讯作者于海斌
中文摘要In laser-induced breakdown spectroscopy (LIBS), plasma emission is extremely unstable because of many factors, such as the fluctuation of laser energy, inhomogeneity of sample surfaces, and variable distance between lens and samples. Therefore, the detection and correction of varying continuum background emission are not easily accomplished. The aim of this work is to present a method that can automatically estimate and correct varying continuum background emission, which is representative in laser-induced plasma. In this method, we first find all minima on a spectrum, and then deduct the unreasonable minima by a proper threshold. Finally, we use one or multiple polynomial functions through the minima left to approximate the continuum backgrounds. The validity of this method was evaluated by using several spectra with different complexities and wavelength ranges. We also applied this method to optimize the measurement time delays of detectors. In addition, for five aluminum alloy samples, we compared their elemental calibration cures between original spectra and background-corrected spectra. Experimental results proved that the method proposed in this paper can well estimate varying continuum backgrounds over a wide range of wavelengths.
WOS标题词Science & Technology ; Technology
类目[WOS]Spectroscopy
研究领域[WOS]Spectroscopy
关键词[WOS]KALMAN FILTER APPROACH ; SPECTROMETRY ; CALIBRATION ; SAMPLES ; PARAMETERS ; REGRESSION
收录类别SCI ; EI
语种英语
WOS记录号WOS:000265755600013
公开日期2012-05-29
源URL[http://ir.sia.cn/handle/173321/7065]  
专题沈阳自动化研究所_工业信息学研究室
推荐引用方式
GB/T 7714
Sun LX,Yu HB. Automatic estimation of varying continuum background emission in laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B: Atomic Spectroscopy,2009,64(3):278-287.
APA Sun LX,&Yu HB.(2009).Automatic estimation of varying continuum background emission in laser-induced breakdown spectroscopy.Spectrochimica Acta Part B: Atomic Spectroscopy,64(3),278-287.
MLA Sun LX,et al."Automatic estimation of varying continuum background emission in laser-induced breakdown spectroscopy".Spectrochimica Acta Part B: Atomic Spectroscopy 64.3(2009):278-287.

入库方式: OAI收割

来源:沈阳自动化研究所

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