Rhodium-catalyzed asymmetric addition of arylboronic acids to gamma-phthalimido-substituted-alpha,beta-unsaturated carboxylic acid esters: an approach to gamma-amino acids
文献类型：期刊论文
| 作者 | Han, Fuzhong ; Chen, Jun ; Zhang, Xiangyang ; Liu, Jibing ; Cun, Linfeng ; Zhu, Jin ; Deng, Jingen ; Liao, Jian |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2011 |
| 卷号 | 52期号:7页码:830-833 |
| ISSN号 | 0040-4039 |
| 关键词 | Bis-sulfoxide ligand 1 Rh-catalyzed 4-Addition gamma-Aminobutyric acids |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China. |
| 产权排序 | 2 |
| 英文摘要 | Efficient Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to ethyl-gamma-phthalimidocrotonate by using bis-sulfoxide ligand affords gamma-aminobutyric acid (GABA) derivatives with high enantioselectivities (90-96% ee) under mild conditions. Optically pure (S)-Baclofen and (S)-Rolipram have been prepared successfully through this synthetic route. (C) 2010 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry |
| 资助信息 | NSFC[20872139, 21072186]; West Light Foundation of CAS; National Basic Research Program of China (973 Program)[2010CB833300]; Chengdu Institute of Biology, CAS[Y0B1051100] |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287340700024 |
| 公开日期 | 2012-11-09 |
| 源URL | [http://210.75.237.14/handle/351003/23560]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Han, Fuzhong,Chen, Jun,Zhang, Xiangyang,et al. Rhodium-catalyzed asymmetric addition of arylboronic acids to gamma-phthalimido-substituted-alpha,beta-unsaturated carboxylic acid esters: an approach to gamma-amino acids[J]. TETRAHEDRON LETTERS,2011,52(7):830-833. |
| APA | Han, Fuzhong.,Chen, Jun.,Zhang, Xiangyang.,Liu, Jibing.,Cun, Linfeng.,...&Liao, Jian.(2011).Rhodium-catalyzed asymmetric addition of arylboronic acids to gamma-phthalimido-substituted-alpha,beta-unsaturated carboxylic acid esters: an approach to gamma-amino acids.TETRAHEDRON LETTERS,52(7),830-833. |
| MLA | Han, Fuzhong,et al."Rhodium-catalyzed asymmetric addition of arylboronic acids to gamma-phthalimido-substituted-alpha,beta-unsaturated carboxylic acid esters: an approach to gamma-amino acids".TETRAHEDRON LETTERS 52.7(2011):830-833. |
入库方式： OAI收割
来源：成都生物研究所
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