Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones
文献类型：期刊论文
| 作者 | Chen, Guihua ; Xing, Junwei ; Cao, Peng ; Liao, Jian |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2012 |
| 卷号 | 68期号:29页码:5908-5911 |
| 关键词 | Chiral sulfinylphosphine 1 Chalcones 4-Addition |
| ISSN号 | 0040-4020 |
| 产权排序 | 2 |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China. |
| 英文摘要 | A general method to obtain enantioenriched 1,3,3-triarylpropan-1-ones bearing a diarylmethine stereocenter was developed using Rh/chiral sulfinylphosphine catalyzed 1,4-addition of arylboronic acids to chalcones. The catalysis progressed smoothly in the presence of 2 mol % catalyst formed in situ from [Rh(C2H4)(2)Cl](2) and chiral tert-butanesulfinylphosphine and gave the adducts with up to 99% yield and 98% ee. (C) 2012 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | NSFC [21072186, 20872139]; West Light Foundation of CAS; Chengdu Institute of Biology of CAS [Y0B1051100]; Major State Basic Research Development Program (973 program) [2010CB833300] |
| 语种 | 英语 |
| WOS记录号 | WOS:000305855800027 |
| 公开日期 | 2013-07-03 |
| 源URL | [http://210.75.237.14/handle/351003/23886]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Chen, Guihua,Xing, Junwei,Cao, Peng,et al. Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones[J]. TETRAHEDRON,2012,68(29):5908-5911. |
| APA | Chen, Guihua,Xing, Junwei,Cao, Peng,&Liao, Jian.(2012).Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones.TETRAHEDRON,68(29),5908-5911. |
| MLA | Chen, Guihua,et al."Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones".TETRAHEDRON 68.29(2012):5908-5911. |
入库方式： OAI收割
来源：成都生物研究所
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