Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions
文献类型：期刊论文
| 作者 | Chen, Guihua ; Gui, Jiangyang ; Cao, Peng ; Liao, Jian |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2012 |
| 卷号 | 68期号:15页码:3220-3224 |
| 关键词 | Sulfoxide-olefin 1 Rh-catalyzed 4-Addition Stereoselectivity reversal |
| ISSN号 | 0040-4020 |
| 产权排序 | 2 |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China. |
| 英文摘要 | A class of chiral sulfoxide-olefins were designed and synthesized through concise routes. Their applications as ligands in Hayashi-Miyaura reaction were studied, which found that vinyl substituents of the ligands vary in stereocontrolling ability. Particularly, either isomer of adducts with excellent ees could be readily obtained through changing the position of the substituents of olefins as well as changing the configuration of the C=C bond of the ligands. Meanwhile, the substrate scope of arylboronic acids and alkenes was clearly shown. (C) 2012 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | NSFC [21072186, 20872139]; West Light Foundation of CAS; Chengdu Institute of Biology of CAS [Y0B1051100]; Major State Basic Research Development Program (973 program) [2010CB833300] |
| 语种 | 英语 |
| WOS记录号 | WOS:000302593200011 |
| 公开日期 | 2013-07-03 |
| 源URL | [http://210.75.237.14/handle/351003/23901]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Chen, Guihua,Gui, Jiangyang,Cao, Peng,et al. Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions[J]. TETRAHEDRON,2012,68(15):3220-3224. |
| APA | Chen, Guihua,Gui, Jiangyang,Cao, Peng,&Liao, Jian.(2012).Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions.TETRAHEDRON,68(15),3220-3224. |
| MLA | Chen, Guihua,et al."Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions".TETRAHEDRON 68.15(2012):3220-3224. |
入库方式： OAI收割
来源：成都生物研究所
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